Visible-Light-Promoted Oxo-Sulfonylation of Ynamides with Sulfonic Acids

Lu Wang; Chengrong Lu; Yanni Yue; Chao Feng

doi:10.1021/acs.orglett.9b00733

Visible-Light-Promoted Oxo-Sulfonylation of Ynamides with Sulfonic Acids

Lu Wang, Chengrong Lu, Yanni Yue, Chao Feng

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

A visible-light-promoted oxo-sulfonylation of ynamides with sulfonic acids is reported, giving rise to a collection of functionalized α-sulfonylated amides in a straightforward manner. The reaction proceeds sequentially through a cascade of electrophilic addition and photoinduced sulfonyl radical-sustained skeleton rearrangement. The high atom economy, mild reaction conditions, and wide substrate scope comprised the merits of this synthetic transformation.

Original language	English
Pages (from-to)	3514-3517
Number of pages	4
Journal	Organic Letters
Volume	21
Issue number	10
DOIs	https://doi.org/10.1021/acs.orglett.9b00733
State	Published - 17 May 2019

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abstract = "A visible-light-promoted oxo-sulfonylation of ynamides with sulfonic acids is reported, giving rise to a collection of functionalized α-sulfonylated amides in a straightforward manner. The reaction proceeds sequentially through a cascade of electrophilic addition and photoinduced sulfonyl radical-sustained skeleton rearrangement. The high atom economy, mild reaction conditions, and wide substrate scope comprised the merits of this synthetic transformation.",

author = "Lu Wang and Chengrong Lu and Yanni Yue and Chao Feng",

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AU - Wang, Lu

AU - Lu, Chengrong

AU - Yue, Yanni

AU - Feng, Chao

PY - 2019/5/17

Y1 - 2019/5/17

N2 - A visible-light-promoted oxo-sulfonylation of ynamides with sulfonic acids is reported, giving rise to a collection of functionalized α-sulfonylated amides in a straightforward manner. The reaction proceeds sequentially through a cascade of electrophilic addition and photoinduced sulfonyl radical-sustained skeleton rearrangement. The high atom economy, mild reaction conditions, and wide substrate scope comprised the merits of this synthetic transformation.

AB - A visible-light-promoted oxo-sulfonylation of ynamides with sulfonic acids is reported, giving rise to a collection of functionalized α-sulfonylated amides in a straightforward manner. The reaction proceeds sequentially through a cascade of electrophilic addition and photoinduced sulfonyl radical-sustained skeleton rearrangement. The high atom economy, mild reaction conditions, and wide substrate scope comprised the merits of this synthetic transformation.

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M3 - 文章

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AN - SCOPUS:85065478017

SN - 1523-7060

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SP - 3514

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JO - Organic Letters

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ER -

Visible-Light-Promoted Oxo-Sulfonylation of Ynamides with Sulfonic Acids

Abstract

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