XAFS and XPS studies on site occupation of Sm3+ ions in Sm doped M-type BaFe12O19

Lixi Wang; Jing Zhang; Qitu Zhang; Naicen Xu; Jie Song

doi:10.1016/j.jmmm.2014.10.097

XAFS and XPS studies on site occupation of Sm³⁺ ions in Sm doped M-type BaFe₁₂O₁₉

Lixi Wang, Jing Zhang, Qitu Zhang, Naicen Xu, Jie Song

College of Materials Science and Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

94 Scopus citations

Abstract

M-type barium hexaferrites doped with Sm³⁺, Ba_1-xSm_xFe₁₂O₁₉ (x=0.00, 0.05, 0.10, 0.15, 0.20, 0.30, 0.50) were prepared by conventional solid state reaction technique. Occupation of Sm³⁺ ions in Ba_1-xSm_xFe₁₂O₁₉ was investigated by X-ray diffraction, X-ray absorption fine structure and X-ray photoelectron spectrum. The changes of crystal cell volume and valency of Sm, Ba and Fe ions indicated that Sm³⁺ occupied Ba²⁺ sites and Fe³⁺ ions were partially reduced to Fe²⁺ ions to keep the valence neutrality.

Original language	English
Pages (from-to)	362-367
Number of pages	6
Journal	Journal of Magnetism and Magnetic Materials
Volume	377
DOIs	https://doi.org/10.1016/j.jmmm.2014.10.097
State	Published - 1 Mar 2015

Keywords

BaFeO
Ions occupation
Substitution
XAFS
XPS

Access to Document

10.1016/j.jmmm.2014.10.097

Cite this

@article{3cd4dabab36b42f7815d1d15671c65cc,

title = "XAFS and XPS studies on site occupation of Sm3+ ions in Sm doped M-type BaFe12O19",

abstract = "M-type barium hexaferrites doped with Sm3+, Ba1-xSmxFe12O19 (x=0.00, 0.05, 0.10, 0.15, 0.20, 0.30, 0.50) were prepared by conventional solid state reaction technique. Occupation of Sm3+ ions in Ba1-xSmxFe12O19 was investigated by X-ray diffraction, X-ray absorption fine structure and X-ray photoelectron spectrum. The changes of crystal cell volume and valency of Sm, Ba and Fe ions indicated that Sm3+ occupied Ba2+ sites and Fe3+ ions were partially reduced to Fe2+ ions to keep the valence neutrality.",

keywords = "BaFeO, Ions occupation, Substitution, XAFS, XPS",

author = "Lixi Wang and Jing Zhang and Qitu Zhang and Naicen Xu and Jie Song",

note = "Publisher Copyright: {\textcopyright} 2014 Elsevier B.V.",

year = "2015",

month = mar,

day = "1",

doi = "10.1016/j.jmmm.2014.10.097",

language = "英语",

volume = "377",

pages = "362--367",

journal = "Journal of Magnetism and Magnetic Materials",

issn = "0304-8853",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - XAFS and XPS studies on site occupation of Sm3+ ions in Sm doped M-type BaFe12O19

AU - Wang, Lixi

AU - Zhang, Jing

AU - Zhang, Qitu

AU - Xu, Naicen

AU - Song, Jie

PY - 2015/3/1

Y1 - 2015/3/1

N2 - M-type barium hexaferrites doped with Sm3+, Ba1-xSmxFe12O19 (x=0.00, 0.05, 0.10, 0.15, 0.20, 0.30, 0.50) were prepared by conventional solid state reaction technique. Occupation of Sm3+ ions in Ba1-xSmxFe12O19 was investigated by X-ray diffraction, X-ray absorption fine structure and X-ray photoelectron spectrum. The changes of crystal cell volume and valency of Sm, Ba and Fe ions indicated that Sm3+ occupied Ba2+ sites and Fe3+ ions were partially reduced to Fe2+ ions to keep the valence neutrality.

AB - M-type barium hexaferrites doped with Sm3+, Ba1-xSmxFe12O19 (x=0.00, 0.05, 0.10, 0.15, 0.20, 0.30, 0.50) were prepared by conventional solid state reaction technique. Occupation of Sm3+ ions in Ba1-xSmxFe12O19 was investigated by X-ray diffraction, X-ray absorption fine structure and X-ray photoelectron spectrum. The changes of crystal cell volume and valency of Sm, Ba and Fe ions indicated that Sm3+ occupied Ba2+ sites and Fe3+ ions were partially reduced to Fe2+ ions to keep the valence neutrality.

KW - BaFeO

KW - Ions occupation

KW - Substitution

KW - XAFS

KW - XPS

UR - http://www.scopus.com/inward/record.url?scp=84911886838&partnerID=8YFLogxK

U2 - 10.1016/j.jmmm.2014.10.097

DO - 10.1016/j.jmmm.2014.10.097

M3 - 文章

AN - SCOPUS:84911886838

SN - 0304-8853

VL - 377

SP - 362

EP - 367

JO - Journal of Magnetism and Magnetic Materials

JF - Journal of Magnetism and Magnetic Materials

ER -

XAFS and XPS studies on site occupation of Sm³⁺ ions in Sm doped M-type BaFe₁₂O₁₉

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this