α-amination of aldehydes catalyzed by in situ generated hypoiodite

Jie Sheng Tian; Kang Wai Jeffrey Ng; Jiun Ru Wong; Teck Peng Loh

doi:10.1002/anie.201204215

α-amination of aldehydes catalyzed by in situ generated hypoiodite

Jie Sheng Tian, Kang Wai Jeffrey Ng, Jiun Ru Wong, Teck Peng Loh

科研成果: 期刊稿件 › 文章 › 同行评审

100 引用（Scopus）

摘要

The metal-free amination of different aldehydes is catalyzed by hypoiodite, which is generated by employing commercially available sodium percarbonate as the co-oxidant. This approach has several advantages: it is a metal-free oxidation that works under mild reaction conditions; furthermore, it has a wide substrate scope and does not give toxic by-products from the co-oxidant that is used.

源语言	英语
页（从-至）	9105-9109
页数	5
期刊	Angewandte Chemie - International Edition
卷	51
期	36
DOI	https://doi.org/10.1002/anie.201204215
出版状态	已出版 - 3 9月 2012
已对外发布	是

访问文件

10.1002/anie.201204215

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{3fbee6ea9016432e8ad95865a0f4609f,

title = "α-amination of aldehydes catalyzed by in situ generated hypoiodite",

abstract = "The metal-free amination of different aldehydes is catalyzed by hypoiodite, which is generated by employing commercially available sodium percarbonate as the co-oxidant. This approach has several advantages: it is a metal-free oxidation that works under mild reaction conditions; furthermore, it has a wide substrate scope and does not give toxic by-products from the co-oxidant that is used.",

keywords = "aldehydes, amination, hypoiodite, sodium percarbonate, α-amino acetal",

author = "Tian, {Jie Sheng} and Ng, {Kang Wai Jeffrey} and Wong, {Jiun Ru} and Loh, {Teck Peng}",

year = "2012",

month = sep,

day = "3",

doi = "10.1002/anie.201204215",

language = "英语",

volume = "51",

pages = "9105--9109",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "36",

}

TY - JOUR

T1 - α-amination of aldehydes catalyzed by in situ generated hypoiodite

AU - Tian, Jie Sheng

AU - Ng, Kang Wai Jeffrey

AU - Wong, Jiun Ru

AU - Loh, Teck Peng

PY - 2012/9/3

Y1 - 2012/9/3

N2 - The metal-free amination of different aldehydes is catalyzed by hypoiodite, which is generated by employing commercially available sodium percarbonate as the co-oxidant. This approach has several advantages: it is a metal-free oxidation that works under mild reaction conditions; furthermore, it has a wide substrate scope and does not give toxic by-products from the co-oxidant that is used.

AB - The metal-free amination of different aldehydes is catalyzed by hypoiodite, which is generated by employing commercially available sodium percarbonate as the co-oxidant. This approach has several advantages: it is a metal-free oxidation that works under mild reaction conditions; furthermore, it has a wide substrate scope and does not give toxic by-products from the co-oxidant that is used.

KW - aldehydes

KW - amination

KW - hypoiodite

KW - sodium percarbonate

KW - α-amino acetal

UR - http://www.scopus.com/inward/record.url?scp=84865847452&partnerID=8YFLogxK

U2 - 10.1002/anie.201204215

DO - 10.1002/anie.201204215

M3 - 文章

AN - SCOPUS:84865847452

SN - 1433-7851

VL - 51

SP - 9105

EP - 9109

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 36

ER -

α-amination of aldehydes catalyzed by in situ generated hypoiodite

摘要

访问文件

其它文件与链接

指纹

引用此