π-Bonding in complexes of benzannulated biscarbenes, -germylenes, and -stannylenes: An experimental and theoretical study

F. Ekkehardt Hahn; Alexander V. Zabula; Tania Pape; Alexander Hepp; Ralf Tonner; Robin Haunschild; Gernot Frenking

doi:10.1002/chem.200801128

π-Bonding in complexes of benzannulated biscarbenes, -germylenes, and -stannylenes: An experimental and theoretical study

F. Ekkehardt Hahn, Alexander V. Zabula, Tania Pape, Alexander Hepp, Ralf Tonner, Robin Haunschild, Gernot Frenking

科研成果: 期刊稿件 › 文章 › 同行评审

56 引用（Scopus）

摘要

Benzannulated bisstannylenes, exhibiting a CH₂C(CH ₃)₂CH₂ linking unit and CH₂tBu (1) or CH₂CH₂CH₂NMe₂ (2) N-substituents, and their molybdenum tetacarbonyl complexes 3 and 4 have been prepared. The complexes 3 and 4 exhibit remarkably short Mo-E bond lengths compared to the related biscarbene and bisgermylene complexes. The experimentally determined bonding parameters of the molybdenum bisstannylene complexes are discussed based on DFT calculations.

源语言	英语
页（从-至）	10716-10721
页数	6
期刊	Chemistry - A European Journal
卷	14
期	34
DOI	https://doi.org/10.1002/chem.200801128
出版状态	已出版 - 26 11月 2008
已对外发布	是

访问文件

10.1002/chem.200801128

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{de60af93852e4ee1a4dbfd272007fd46,

title = "π-Bonding in complexes of benzannulated biscarbenes, -germylenes, and -stannylenes: An experimental and theoretical study",

abstract = "Benzannulated bisstannylenes, exhibiting a CH2C(CH 3)2CH2 linking unit and CH2tBu (1) or CH2CH2CH2NMe2 (2) N-substituents, and their molybdenum tetacarbonyl complexes 3 and 4 have been prepared. The complexes 3 and 4 exhibit remarkably short Mo-E bond lengths compared to the related biscarbene and bisgermylene complexes. The experimentally determined bonding parameters of the molybdenum bisstannylene complexes are discussed based on DFT calculations.",

keywords = "Carbene analogues, Coordination modes, Stannylenes, Tin",

author = "Hahn, {F. Ekkehardt} and Zabula, {Alexander V.} and Tania Pape and Alexander Hepp and Ralf Tonner and Robin Haunschild and Gernot Frenking",

year = "2008",

month = nov,

day = "26",

doi = "10.1002/chem.200801128",

language = "英语",

volume = "14",

pages = "10716--10721",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley and Sons Inc",

number = "34",

}

TY - JOUR

T1 - π-Bonding in complexes of benzannulated biscarbenes, -germylenes, and -stannylenes

T2 - An experimental and theoretical study

AU - Hahn, F. Ekkehardt

AU - Zabula, Alexander V.

AU - Pape, Tania

AU - Hepp, Alexander

AU - Tonner, Ralf

AU - Haunschild, Robin

AU - Frenking, Gernot

PY - 2008/11/26

Y1 - 2008/11/26

N2 - Benzannulated bisstannylenes, exhibiting a CH2C(CH 3)2CH2 linking unit and CH2tBu (1) or CH2CH2CH2NMe2 (2) N-substituents, and their molybdenum tetacarbonyl complexes 3 and 4 have been prepared. The complexes 3 and 4 exhibit remarkably short Mo-E bond lengths compared to the related biscarbene and bisgermylene complexes. The experimentally determined bonding parameters of the molybdenum bisstannylene complexes are discussed based on DFT calculations.

AB - Benzannulated bisstannylenes, exhibiting a CH2C(CH 3)2CH2 linking unit and CH2tBu (1) or CH2CH2CH2NMe2 (2) N-substituents, and their molybdenum tetacarbonyl complexes 3 and 4 have been prepared. The complexes 3 and 4 exhibit remarkably short Mo-E bond lengths compared to the related biscarbene and bisgermylene complexes. The experimentally determined bonding parameters of the molybdenum bisstannylene complexes are discussed based on DFT calculations.

KW - Carbene analogues

KW - Coordination modes

KW - Stannylenes

KW - Tin

UR - http://www.scopus.com/inward/record.url?scp=56749131173&partnerID=8YFLogxK

U2 - 10.1002/chem.200801128

DO - 10.1002/chem.200801128

M3 - 文章

AN - SCOPUS:56749131173

SN - 0947-6539

VL - 14

SP - 10716

EP - 10721

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 34

ER -

π-Bonding in complexes of benzannulated biscarbenes, -germylenes, and -stannylenes: An experimental and theoretical study

摘要

访问文件

其它文件与链接

指纹

引用此