生物基（甲基）丙烯酸酯的合成及其聚合物制备

As an important family of synthetic polymers，poly（meth）acrylates have a wide range of applications in the fields of coatings，adhesives，biomedines，electronic and electrical materials. However，the（meth）acrylates monomers are mainly derived from petrochemical resources. Transformations of biomass into（meth）acrylate monomers and polymers have attracted growing research interest from the viewpoint of sustainability. The bio-based poly（meth）acrylates not only serve as the supplement for the fossil based product but also provide great chance for the development of value-added high performance materials with designed novel structures. This article highlights the recent progress in the synthesis and polymerization of bio-based（meth）acrylates. The lignin，terpene，plant oil，glucose，isosorbide，and furan derivatives as the biomass feedstock are respectively reviewed in consecutive order. The properties and applications of the corresponding bio-based poly（meth）acrylates are summarized. Moreover，the challenges and opportunities of bio-based poly（meth）acrylates are also discussed.