1,1-二叔戊基过氧环己烷热危险性分析

Wei Zhang; Juncheng Jiang; Mengya Zou; Jianbo Chu

doi:10.16265/j.cnki.issn1003-3033.2019.02.014

1,1-二叔戊基过氧环己烷热危险性分析

Wei Zhang, Juncheng Jiang, Mengya Zou, Jianbo Chu

安全科学与工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

To investigate the thermal hazard of DTAC, DSC was used to test the thermal decomposition characteristics of DTAC, were studied by using DSC, and its kinetic parameters of thermal decomposition were determined by using Friedman method. The thermal decomposition behavior of DTAC under adiabatic conditions was studied by ARC. According to the caculated kinetic parameters, the relationship between the time to maximum rate(TMRad)of DTAC decomposition and temperature, and that between SADT and heat transfer coefficient were obtained. It is discovered that SADT of the 25 kg DTAC solution packed by high density polyethylene (HDPE) is 57. 3 ℃, which calls for package material with a larger heat transfer coefficient and additional care of temperature during transportation.

投稿的翻译标题	Thermal hazard analysis of 1, 1-di (tert-amylperoxy) cyclohexane
源语言	繁体中文
页（从-至）	82-87
页数	6
期刊	China Safety Science Journal
卷	29
期	2
DOI	https://doi.org/10.16265/j.cnki.issn1003-3033.2019.02.014
出版状态	已出版 - 2月 2019

关键词

1,1-di(tert-amylperoxy) cyclohexane (DTAC)
Friedman method
accelerating rate calorimeter(ARC)
differential scanning calorimeter (DSC)
self-accelerating decomposition temperature (SADT)
thermal decomposition characteristics

联合国可持续发展目标

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10.16265/j.cnki.issn1003-3033.2019.02.014

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引用此

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title = "1,1-二叔戊基过氧环己烷热危险性分析",

abstract = "To investigate the thermal hazard of DTAC, DSC was used to test the thermal decomposition characteristics of DTAC, were studied by using DSC, and its kinetic parameters of thermal decomposition were determined by using Friedman method. The thermal decomposition behavior of DTAC under adiabatic conditions was studied by ARC. According to the caculated kinetic parameters, the relationship between the time to maximum rate(TMRad)of DTAC decomposition and temperature, and that between SADT and heat transfer coefficient were obtained. It is discovered that SADT of the 25 kg DTAC solution packed by high density polyethylene (HDPE) is 57. 3 ℃, which calls for package material with a larger heat transfer coefficient and additional care of temperature during transportation.",

keywords = "1,1-di(tert-amylperoxy) cyclohexane (DTAC), Friedman method, accelerating rate calorimeter(ARC), differential scanning calorimeter (DSC), self-accelerating decomposition temperature (SADT), thermal decomposition characteristics",

author = "Wei Zhang and Juncheng Jiang and Mengya Zou and Jianbo Chu",

year = "2019",

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TY - JOUR

T1 - 1,1-二叔戊基过氧环己烷热危险性分析

AU - Zhang, Wei

AU - Jiang, Juncheng

AU - Zou, Mengya

AU - Chu, Jianbo

PY - 2019/2

Y1 - 2019/2

N2 - To investigate the thermal hazard of DTAC, DSC was used to test the thermal decomposition characteristics of DTAC, were studied by using DSC, and its kinetic parameters of thermal decomposition were determined by using Friedman method. The thermal decomposition behavior of DTAC under adiabatic conditions was studied by ARC. According to the caculated kinetic parameters, the relationship between the time to maximum rate(TMRad)of DTAC decomposition and temperature, and that between SADT and heat transfer coefficient were obtained. It is discovered that SADT of the 25 kg DTAC solution packed by high density polyethylene (HDPE) is 57. 3 ℃, which calls for package material with a larger heat transfer coefficient and additional care of temperature during transportation.

AB - To investigate the thermal hazard of DTAC, DSC was used to test the thermal decomposition characteristics of DTAC, were studied by using DSC, and its kinetic parameters of thermal decomposition were determined by using Friedman method. The thermal decomposition behavior of DTAC under adiabatic conditions was studied by ARC. According to the caculated kinetic parameters, the relationship between the time to maximum rate(TMRad)of DTAC decomposition and temperature, and that between SADT and heat transfer coefficient were obtained. It is discovered that SADT of the 25 kg DTAC solution packed by high density polyethylene (HDPE) is 57. 3 ℃, which calls for package material with a larger heat transfer coefficient and additional care of temperature during transportation.

KW - 1,1-di(tert-amylperoxy) cyclohexane (DTAC)

KW - Friedman method

KW - accelerating rate calorimeter(ARC)

KW - differential scanning calorimeter (DSC)

KW - self-accelerating decomposition temperature (SADT)

KW - thermal decomposition characteristics

UR - http://www.scopus.com/inward/record.url?scp=85159202494&partnerID=8YFLogxK

U2 - 10.16265/j.cnki.issn1003-3033.2019.02.014

DO - 10.16265/j.cnki.issn1003-3033.2019.02.014

M3 - 文章

AN - SCOPUS:85159202494

SN - 1003-3033

VL - 29

SP - 82

EP - 87

JO - China Safety Science Journal

JF - China Safety Science Journal

IS - 2

ER -

1,1-二叔戊基过氧环己烷热危险性分析

摘要

关键词

联合国可持续发展目标

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引用此