2-Diphenylphosphino-2′-hydroxy-1,1′-binaphthyl as a chiral auxiliary for asymmetric coordination chemistry

Lei Gong; Christian Müller; Mehmet Ali Celik; Gernot Frenking; Eric Meggers

doi:10.1039/c0nj00787k

2-Diphenylphosphino-2′-hydroxy-1,1′-binaphthyl as a chiral auxiliary for asymmetric coordination chemistry

Lei Gong, Christian Müller, Mehmet Ali Celik, Gernot Frenking, Eric Meggers

University of Marburg

科研成果: 期刊稿件 › 文章 › 同行评审

11 引用（Scopus）

摘要

In this study, the bidentate ligand (R)-2-diphenylphosphino-2′- hydroxy-1,1′-binaphthyl (HO-MOP) was investigated as a chiral auxiliary for the asymmetric synthesis of ruthenium polypyridyl complexes. It was found that (R)-HO-MOP serves as an effective chiral auxiliary starting from different precursor complexes, most notably using the commercially available half-sandwich complex [Ru(η⁶-C₆H₆)Cl₂] ₂.

源语言	英语
页（从-至）	788-793
页数	6
期刊	New Journal of Chemistry
卷	35
期	4
DOI	https://doi.org/10.1039/c0nj00787k
出版状态	已出版 - 4月 2011
已对外发布	是

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abstract = "In this study, the bidentate ligand (R)-2-diphenylphosphino-2′- hydroxy-1,1′-binaphthyl (HO-MOP) was investigated as a chiral auxiliary for the asymmetric synthesis of ruthenium polypyridyl complexes. It was found that (R)-HO-MOP serves as an effective chiral auxiliary starting from different precursor complexes, most notably using the commercially available half-sandwich complex [Ru(η6-C6H6)Cl2] 2.",

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AU - Gong, Lei

AU - Müller, Christian

AU - Celik, Mehmet Ali

AU - Frenking, Gernot

AU - Meggers, Eric

PY - 2011/4

Y1 - 2011/4

N2 - In this study, the bidentate ligand (R)-2-diphenylphosphino-2′- hydroxy-1,1′-binaphthyl (HO-MOP) was investigated as a chiral auxiliary for the asymmetric synthesis of ruthenium polypyridyl complexes. It was found that (R)-HO-MOP serves as an effective chiral auxiliary starting from different precursor complexes, most notably using the commercially available half-sandwich complex [Ru(η6-C6H6)Cl2] 2.

AB - In this study, the bidentate ligand (R)-2-diphenylphosphino-2′- hydroxy-1,1′-binaphthyl (HO-MOP) was investigated as a chiral auxiliary for the asymmetric synthesis of ruthenium polypyridyl complexes. It was found that (R)-HO-MOP serves as an effective chiral auxiliary starting from different precursor complexes, most notably using the commercially available half-sandwich complex [Ru(η6-C6H6)Cl2] 2.

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2-Diphenylphosphino-2′-hydroxy-1,1′-binaphthyl as a chiral auxiliary for asymmetric coordination chemistry

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