TY - JOUR
T1 - A coordination polymer with a (3,4)-connected (6 2.8) 2(6 2.8 4) 3d network
T2 - Synthesis, crystal structure and luminescent properties
AU - Liu, Guang Xiang
AU - Guo, Wei
AU - Nishihara, Sadafumi
AU - Ren, Xiao Ming
PY - 2012/10/1
Y1 - 2012/10/1
N2 - The 3D Cd(II) coordination polymer Cd 2(ODPA)(bpe)(py) (H 2O) 2 (1) with 3,3',4,4'-oxydiphthalic acid (H 4ODPA) and 1,2- bis(4-pyridyl)ethane (bpe) was synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectrum, and single-crystal X-ray diffraction techniques. X-ray crystallographic studies of 1 reveal that this metal-organic complex has an interesting (3,4)-connected 3D network with binary nodes. The Cd atoms are three-connected nodes and the ODPA ligands are fourconnected nodes. Luminescent study indicates 1 has an emissive maximum at 408 nm in the solid state at room temperature.
AB - The 3D Cd(II) coordination polymer Cd 2(ODPA)(bpe)(py) (H 2O) 2 (1) with 3,3',4,4'-oxydiphthalic acid (H 4ODPA) and 1,2- bis(4-pyridyl)ethane (bpe) was synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectrum, and single-crystal X-ray diffraction techniques. X-ray crystallographic studies of 1 reveal that this metal-organic complex has an interesting (3,4)-connected 3D network with binary nodes. The Cd atoms are three-connected nodes and the ODPA ligands are fourconnected nodes. Luminescent study indicates 1 has an emissive maximum at 408 nm in the solid state at room temperature.
KW - Cd(II) coordination polymer
KW - Luminescence
KW - Polycarboxylate
KW - Topology
UR - http://www.scopus.com/inward/record.url?scp=84867445888&partnerID=8YFLogxK
U2 - 10.1080/15533174.2012.680092
DO - 10.1080/15533174.2012.680092
M3 - 文章
AN - SCOPUS:84867445888
SN - 1553-3174
VL - 42
SP - 1222
EP - 1226
JO - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
JF - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
IS - 9
ER -