A dimer of silaisonitrile with two-coordinate silicon atoms

Rajendra S. Ghadwal; Herbert W. Roesky; Kevin Pröpper; Birger Dittrich; Susanne Klein; Gernot Frenking

doi:10.1002/anie.201101320

A dimer of silaisonitrile with two-coordinate silicon atoms

Rajendra S. Ghadwal, Herbert W. Roesky, Kevin Pröpper, Birger Dittrich, Susanne Klein, Gernot Frenking

科研成果: 期刊稿件 › 文章 › 同行评审

84 引用（Scopus）

摘要

A specialty of silicon: A stable dimeric silaisonitrile (ArNSi:) ₂ (see picture; Ar=2,6-bis(2,4,6-triisopropylphenyl)phenyl) was prepared by the reduction of dichlorosilaimine IPrCl₂SiNAr with KC₈. The dimer is the first base-free disilylene with two-coordinate silicon atoms; reaction with trimethylsilyl azide affords the first bis(silaimine) (ArNSiNSiMe₃)₂ with three-coordinate silicon atoms.

源语言	英语
页（从-至）	5374-5378
页数	5
期刊	Angewandte Chemie - International Edition
卷	50
期	23
DOI	https://doi.org/10.1002/anie.201101320
出版状态	已出版 - 27 5月 2011
已对外发布	是

访问文件

10.1002/anie.201101320

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{2bd37a0e9c374cc1b5352a91ad2b01b3,

title = "A dimer of silaisonitrile with two-coordinate silicon atoms",

abstract = "A specialty of silicon: A stable dimeric silaisonitrile (ArNSi:) 2 (see picture; Ar=2,6-bis(2,4,6-triisopropylphenyl)phenyl) was prepared by the reduction of dichlorosilaimine IPrCl2SiNAr with KC8. The dimer is the first base-free disilylene with two-coordinate silicon atoms; reaction with trimethylsilyl azide affords the first bis(silaimine) (ArNSiNSiMe3)2 with three-coordinate silicon atoms.",

keywords = "X-ray diffraction, density functional calculations, main-group elements, multiple bonds, silylenes",

author = "Ghadwal, {Rajendra S.} and Roesky, {Herbert W.} and Kevin Pr{\"o}pper and Birger Dittrich and Susanne Klein and Gernot Frenking",

year = "2011",

month = may,

day = "27",

doi = "10.1002/anie.201101320",

language = "英语",

volume = "50",

pages = "5374--5378",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "23",

}

TY - JOUR

T1 - A dimer of silaisonitrile with two-coordinate silicon atoms

AU - Ghadwal, Rajendra S.

AU - Roesky, Herbert W.

AU - Pröpper, Kevin

AU - Dittrich, Birger

AU - Klein, Susanne

AU - Frenking, Gernot

PY - 2011/5/27

Y1 - 2011/5/27

N2 - A specialty of silicon: A stable dimeric silaisonitrile (ArNSi:) 2 (see picture; Ar=2,6-bis(2,4,6-triisopropylphenyl)phenyl) was prepared by the reduction of dichlorosilaimine IPrCl2SiNAr with KC8. The dimer is the first base-free disilylene with two-coordinate silicon atoms; reaction with trimethylsilyl azide affords the first bis(silaimine) (ArNSiNSiMe3)2 with three-coordinate silicon atoms.

AB - A specialty of silicon: A stable dimeric silaisonitrile (ArNSi:) 2 (see picture; Ar=2,6-bis(2,4,6-triisopropylphenyl)phenyl) was prepared by the reduction of dichlorosilaimine IPrCl2SiNAr with KC8. The dimer is the first base-free disilylene with two-coordinate silicon atoms; reaction with trimethylsilyl azide affords the first bis(silaimine) (ArNSiNSiMe3)2 with three-coordinate silicon atoms.

KW - X-ray diffraction

KW - density functional calculations

KW - main-group elements

KW - multiple bonds

KW - silylenes

UR - http://www.scopus.com/inward/record.url?scp=79957531327&partnerID=8YFLogxK

U2 - 10.1002/anie.201101320

DO - 10.1002/anie.201101320

M3 - 文章

AN - SCOPUS:79957531327

SN - 1433-7851

VL - 50

SP - 5374

EP - 5378

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 23

ER -

A dimer of silaisonitrile with two-coordinate silicon atoms

摘要

访问文件

其它文件与链接

指纹

引用此