A general strategy for the introduction of stereogenic centers bearing a methyl group: Total synthesis of sex pheromones

Shun Yi Wang, Ping Song, Yen Jin Chin, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

9 引用 (Scopus)

摘要

We're bringing sexy back: The highly efficient introduction of stereogenic centers bearing methyl group by conjugate addition of RMgBr to α,β-unsaturated esters has been employed in the total syntheses of two sex pheromones (see scheme). Binap=[1,1'-binaphthalene]-2,2'- diylbis(diphenylphosphane).

源语言英语
页(从-至)385-388
页数4
期刊Chemistry - An Asian Journal
6
2
DOI
出版状态已出版 - 1 2月 2011
已对外发布

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