TY - JOUR
T1 - A Green Route to a Na2FePO4F-Based Cathode for Sodium Ion Batteries of High Rate and Long Cycling Life
AU - Deng, Xiang
AU - Shi, Wenxiang
AU - Sunarso, Jaka
AU - Liu, Meilin
AU - Shao, Zongping
N1 - Publisher Copyright:
© 2017 American Chemical Society.
PY - 2017/5/17
Y1 - 2017/5/17
N2 - Sodium ion batteries (SIBs) are considered one of the most promising alternatives for large-scale energy storage due largely to the abundance and low cost of sodium. However, the lack of high-performance cathode materials at low cost represents a major obstacle toward broad commercialization of SIB technology. In this work, we report a green route strategy that allows cost-effective fabrication of carbon-coated Na2FePO4F cathode for SIBs. By using vitamin C as a green organic carbon source and environmentally friendly water-based polyacrylic latex as the binder, we have demonstrated that the Na2FePO4F phase in the as-derived Na2FePO4F/C electrode shows a high reversible capacity of 117 mAh g-1 at a cycling rate of 0.1 C. More attractively, excellent rate capability is achieved while retaining outstanding cycling stability (∼85% capacity retention after 1000 charge-discharge cycles at a rate of 4 C). Further, in operando X-ray diffraction has been used to probe the evolution of phase structures during the charge-discharge process, confirming the structural robustness of the Na2FePO4F/C cathode (even when charged to 4.5 V). Accordingly, the poor initial Coulombic efficiency of some anode materials may be compensated by extracting more sodium ions from Na2FePO4F/C cathode at higher potentials (up to 4.5 V).
AB - Sodium ion batteries (SIBs) are considered one of the most promising alternatives for large-scale energy storage due largely to the abundance and low cost of sodium. However, the lack of high-performance cathode materials at low cost represents a major obstacle toward broad commercialization of SIB technology. In this work, we report a green route strategy that allows cost-effective fabrication of carbon-coated Na2FePO4F cathode for SIBs. By using vitamin C as a green organic carbon source and environmentally friendly water-based polyacrylic latex as the binder, we have demonstrated that the Na2FePO4F phase in the as-derived Na2FePO4F/C electrode shows a high reversible capacity of 117 mAh g-1 at a cycling rate of 0.1 C. More attractively, excellent rate capability is achieved while retaining outstanding cycling stability (∼85% capacity retention after 1000 charge-discharge cycles at a rate of 4 C). Further, in operando X-ray diffraction has been used to probe the evolution of phase structures during the charge-discharge process, confirming the structural robustness of the Na2FePO4F/C cathode (even when charged to 4.5 V). Accordingly, the poor initial Coulombic efficiency of some anode materials may be compensated by extracting more sodium ions from Na2FePO4F/C cathode at higher potentials (up to 4.5 V).
KW - NaFePOF
KW - carbon coating
KW - environmentally friendly cathode
KW - green electrode fabrication
KW - sodium ion batteries
UR - http://www.scopus.com/inward/record.url?scp=85019611916&partnerID=8YFLogxK
U2 - 10.1021/acsami.7b03933
DO - 10.1021/acsami.7b03933
M3 - 文章
C2 - 28453932
AN - SCOPUS:85019611916
SN - 1944-8244
VL - 9
SP - 16280
EP - 16287
JO - ACS Applied Materials and Interfaces
JF - ACS Applied Materials and Interfaces
IS - 19
ER -