A highly stable multifunctional three-dimensional microporous framework: Excellent selective sorption and visible photoluminescence

Yumei Huang; Xiaofang Zheng; Jingui Duan; Wenlong Liu; Li Zhou; Chenggang Wang; Lili Wen; Jinbo Zhao; Dongfeng Li

doi:10.1039/c4dt00230j

A highly stable multifunctional three-dimensional microporous framework: Excellent selective sorption and visible photoluminescence

Yumei Huang, Xiaofang Zheng, Jingui Duan, Wenlong Liu, Li Zhou, Chenggang Wang, Lili Wen, Jinbo Zhao, Dongfeng Li

科研成果: 期刊稿件 › 文章 › 同行评审

16 引用（Scopus）

摘要

A Cd(ii)-MOF [Cd(L)(DMF)] (1) (H₂L = 5-(4-pyridyl)-isophthalic acid) featuring high thermal and chemical stability has been solvothermally synthesized and characterized. Complex 1 is a robust multifunctional three-dimensional (3D) microporous framework possessing an unusual (4,5)-connected topological net. Activated 1 shows high-efficiency for the selective capture of CO₂ over N₂ and CH₄ under ambient conditions, which ranks it among MOFs with the highest selectivity. In addition, desolvated 1 exhibits good separation ratios of H₂ over N₂ at lower temperature, as well as alcohols from water. In particular, desolvated 1 demonstrates significantly higher adsorption enthalpies for CO₂ and CH₄ gas molecules, which are in the range of the highest Q_st values reported to date. Furthermore, complex 1 displays visible photoluminescence in the solid state under UV irradiation. This journal is

源语言	英语
页（从-至）	6811-6818
页数	8
期刊	Dalton Transactions
卷	43
期	18
DOI	https://doi.org/10.1039/c4dt00230j
出版状态	已出版 - 14 5月 2014
已对外发布	是

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T2 - Excellent selective sorption and visible photoluminescence

AU - Huang, Yumei

AU - Zheng, Xiaofang

AU - Duan, Jingui

AU - Liu, Wenlong

AU - Zhou, Li

AU - Wang, Chenggang

AU - Wen, Lili

AU - Zhao, Jinbo

AU - Li, Dongfeng

PY - 2014/5/14

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N2 - A Cd(ii)-MOF [Cd(L)(DMF)] (1) (H2L = 5-(4-pyridyl)-isophthalic acid) featuring high thermal and chemical stability has been solvothermally synthesized and characterized. Complex 1 is a robust multifunctional three-dimensional (3D) microporous framework possessing an unusual (4,5)-connected topological net. Activated 1 shows high-efficiency for the selective capture of CO2 over N2 and CH4 under ambient conditions, which ranks it among MOFs with the highest selectivity. In addition, desolvated 1 exhibits good separation ratios of H2 over N2 at lower temperature, as well as alcohols from water. In particular, desolvated 1 demonstrates significantly higher adsorption enthalpies for CO2 and CH4 gas molecules, which are in the range of the highest Qst values reported to date. Furthermore, complex 1 displays visible photoluminescence in the solid state under UV irradiation. This journal is

AB - A Cd(ii)-MOF [Cd(L)(DMF)] (1) (H2L = 5-(4-pyridyl)-isophthalic acid) featuring high thermal and chemical stability has been solvothermally synthesized and characterized. Complex 1 is a robust multifunctional three-dimensional (3D) microporous framework possessing an unusual (4,5)-connected topological net. Activated 1 shows high-efficiency for the selective capture of CO2 over N2 and CH4 under ambient conditions, which ranks it among MOFs with the highest selectivity. In addition, desolvated 1 exhibits good separation ratios of H2 over N2 at lower temperature, as well as alcohols from water. In particular, desolvated 1 demonstrates significantly higher adsorption enthalpies for CO2 and CH4 gas molecules, which are in the range of the highest Qst values reported to date. Furthermore, complex 1 displays visible photoluminescence in the solid state under UV irradiation. This journal is

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A highly stable multifunctional three-dimensional microporous framework: Excellent selective sorption and visible photoluminescence

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