A new mesoporous coordination polymer: Synthesis, structure, and gas adsorption studies

Jingui Duan; Qianqian Li; Zhiyong Lu

doi:10.1039/c5ce00015g

A new mesoporous coordination polymer: Synthesis, structure, and gas adsorption studies

Jingui Duan, Qianqian Li, Zhiyong Lu

化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

13 引用（Scopus）

摘要

A new porous coordination framework, [Cu₃(BTN)₂(H₂O)₃]·xGuest (NJTU-1), with a large aromatic organic surface and remarkable mesopores, was synthesized and structurally characterized. It exhibits the second highest BET surface area of 2800 m² g^-1 among the interpenetrated PCPs. Additionally, this PCP also demonstrates high CH₄ (excess amount: 174 cm³ g^-1), C₂H₄ (220 cm³ g^-1), C₂H₆ (299 cm³ g^-1) and CO₂ (298 cm³ g^-1) uptake capacities as well as good adsorption selectivities for C₂H₄ (12-145), C₂H₆ (15.5-380) and CO₂ (7.1-31.6) over CH₄ at 298 K.

源语言	英语
页（从-至）	2087-2090
页数	4
期刊	CrystEngComm
卷	17
期	10
DOI	https://doi.org/10.1039/c5ce00015g
出版状态	已出版 - 14 3月 2015

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10.1039/c5ce00015g

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title = "A new mesoporous coordination polymer: Synthesis, structure, and gas adsorption studies",

abstract = "A new porous coordination framework, [Cu3(BTN)2(H2O)3]·xGuest (NJTU-1), with a large aromatic organic surface and remarkable mesopores, was synthesized and structurally characterized. It exhibits the second highest BET surface area of 2800 m2 g-1 among the interpenetrated PCPs. Additionally, this PCP also demonstrates high CH4 (excess amount: 174 cm3 g-1), C2H4 (220 cm3 g-1), C2H6 (299 cm3 g-1) and CO2 (298 cm3 g-1) uptake capacities as well as good adsorption selectivities for C2H4 (12-145), C2H6 (15.5-380) and CO2 (7.1-31.6) over CH4 at 298 K.",

author = "Jingui Duan and Qianqian Li and Zhiyong Lu",

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AU - Duan, Jingui

AU - Li, Qianqian

AU - Lu, Zhiyong

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Y1 - 2015/3/14

N2 - A new porous coordination framework, [Cu3(BTN)2(H2O)3]·xGuest (NJTU-1), with a large aromatic organic surface and remarkable mesopores, was synthesized and structurally characterized. It exhibits the second highest BET surface area of 2800 m2 g-1 among the interpenetrated PCPs. Additionally, this PCP also demonstrates high CH4 (excess amount: 174 cm3 g-1), C2H4 (220 cm3 g-1), C2H6 (299 cm3 g-1) and CO2 (298 cm3 g-1) uptake capacities as well as good adsorption selectivities for C2H4 (12-145), C2H6 (15.5-380) and CO2 (7.1-31.6) over CH4 at 298 K.

AB - A new porous coordination framework, [Cu3(BTN)2(H2O)3]·xGuest (NJTU-1), with a large aromatic organic surface and remarkable mesopores, was synthesized and structurally characterized. It exhibits the second highest BET surface area of 2800 m2 g-1 among the interpenetrated PCPs. Additionally, this PCP also demonstrates high CH4 (excess amount: 174 cm3 g-1), C2H4 (220 cm3 g-1), C2H6 (299 cm3 g-1) and CO2 (298 cm3 g-1) uptake capacities as well as good adsorption selectivities for C2H4 (12-145), C2H6 (15.5-380) and CO2 (7.1-31.6) over CH4 at 298 K.

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A new mesoporous coordination polymer: Synthesis, structure, and gas adsorption studies

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