A new method for the synthesis of β,γ-unsaturated amides from allylic carbonate catalyzed by palladium in the presence of carbon monoxide and amine: Studies towards the total synthesis of antillatoxin

Teck Peng Loh, Guo Qiang Cao, Zheng Yin

科研成果: 期刊稿件文章同行评审

16 引用 (Scopus)

摘要

The reaction of α,β-unsaturated carbonates was carried out in DMF in the presence of PdCl2/dppb (5 mol%), CO and L-alanine at 65 °C for 4 days to give the β,γ-unsaturated amide intermediate of antillatoxin in good yield.

源语言英语
页(从-至)2649-2652
页数4
期刊Tetrahedron Letters
40
13
DOI
出版状态已出版 - 26 3月 1999
已对外发布

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