摘要
A new, simple, and efficient preparation of symmetrical and unsymmetrical carbodiimides from the corresponding thioureas via dehydrosulfurization using a hypervalent iodine(III) reagent is described. The oxidation afforded carbodiimides in excellent yields and high selectivity. A possible mechanism for the transformation is proposed.
| 源语言 | 英语 |
|---|---|
| 页（从-至） | 711-714 |
| 页数 | 4 |
| 期刊 | Synthesis (Germany) |
| 期 | 5 |
| DOI | |
| 出版状态 | 已出版 - 2011 |
| 已对外发布 | 是 |