A novel dumbbell-like polyoxometalate assembled of copper(II)-disubstituted monovacant Keggin polyoxoanions with a tetranuclear copper cluster

Hao Miao; Xiao Xu; Wei Wei Ju; Hong Xiang Wan; Yu Zhang; Dun Ru Zhu; Yan Xu

doi:10.1021/ic5000827

A novel dumbbell-like polyoxometalate assembled of copper(II)-disubstituted monovacant Keggin polyoxoanions with a tetranuclear copper cluster

Hao Miao, Xiao Xu, Wei Wei Ju, Hong Xiang Wan, Yu Zhang, Dun Ru Zhu, Yan Xu

科研成果: 期刊稿件 › 文章 › 同行评审

36 引用（Scopus）

摘要

A dimeric Keggin polyoxometalate, [Cu(bpy)(μ₂-OH)] ₄[(H₂O)(bpy)₂HPW₁₁Cu ₂O₃₉]₂·2CH₃CH ₂OH·10H₂O (1), constructed from two dicopper(II)-substituted monovacant Keggin polyoxoanions bridged by a Cu ₄ cluster, has been hydrothermally synthesized. Magnetic analysis indicates predominantly an antiferromagnetic interaction between copper(II) centers. Compound 1 also shows very high catalytic activity for the esterification of phosphoric acid with equimolar lauryl alcohol to monoalkyl phosphate ester.

源语言	英语
页（从-至）	2757-2759
页数	3
期刊	Inorganic Chemistry
卷	53
期	6
DOI	https://doi.org/10.1021/ic5000827
出版状态	已出版 - 17 3月 2014

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title = "A novel dumbbell-like polyoxometalate assembled of copper(II)-disubstituted monovacant Keggin polyoxoanions with a tetranuclear copper cluster",

abstract = "A dimeric Keggin polyoxometalate, [Cu(bpy)(μ2-OH)] 4[(H2O)(bpy)2HPW11Cu 2O39]2·2CH3CH 2OH·10H2O (1), constructed from two dicopper(II)-substituted monovacant Keggin polyoxoanions bridged by a Cu 4 cluster, has been hydrothermally synthesized. Magnetic analysis indicates predominantly an antiferromagnetic interaction between copper(II) centers. Compound 1 also shows very high catalytic activity for the esterification of phosphoric acid with equimolar lauryl alcohol to monoalkyl phosphate ester.",

author = "Hao Miao and Xiao Xu and Ju, {Wei Wei} and Wan, {Hong Xiang} and Yu Zhang and Zhu, {Dun Ru} and Yan Xu",

year = "2014",

month = mar,

day = "17",

doi = "10.1021/ic5000827",

language = "英语",

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T1 - A novel dumbbell-like polyoxometalate assembled of copper(II)-disubstituted monovacant Keggin polyoxoanions with a tetranuclear copper cluster

AU - Miao, Hao

AU - Xu, Xiao

AU - Ju, Wei Wei

AU - Wan, Hong Xiang

AU - Zhang, Yu

AU - Zhu, Dun Ru

AU - Xu, Yan

PY - 2014/3/17

Y1 - 2014/3/17

N2 - A dimeric Keggin polyoxometalate, [Cu(bpy)(μ2-OH)] 4[(H2O)(bpy)2HPW11Cu 2O39]2·2CH3CH 2OH·10H2O (1), constructed from two dicopper(II)-substituted monovacant Keggin polyoxoanions bridged by a Cu 4 cluster, has been hydrothermally synthesized. Magnetic analysis indicates predominantly an antiferromagnetic interaction between copper(II) centers. Compound 1 also shows very high catalytic activity for the esterification of phosphoric acid with equimolar lauryl alcohol to monoalkyl phosphate ester.

AB - A dimeric Keggin polyoxometalate, [Cu(bpy)(μ2-OH)] 4[(H2O)(bpy)2HPW11Cu 2O39]2·2CH3CH 2OH·10H2O (1), constructed from two dicopper(II)-substituted monovacant Keggin polyoxoanions bridged by a Cu 4 cluster, has been hydrothermally synthesized. Magnetic analysis indicates predominantly an antiferromagnetic interaction between copper(II) centers. Compound 1 also shows very high catalytic activity for the esterification of phosphoric acid with equimolar lauryl alcohol to monoalkyl phosphate ester.

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DO - 10.1021/ic5000827

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VL - 53

SP - 2757

EP - 2759

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -

A novel dumbbell-like polyoxometalate assembled of copper(II)-disubstituted monovacant Keggin polyoxoanions with a tetranuclear copper cluster

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