A porous polymer electrolyte based on P(VDF-HFP) prepared by a simple phase separation process

G. C. Li; P. Zhang; H. P. Zhang; L. C. Yang; Y. P. Wu

doi:10.1016/j.elecom.2008.09.035

A porous polymer electrolyte based on P(VDF-HFP) prepared by a simple phase separation process

G. C. Li, P. Zhang, H. P. Zhang, L. C. Yang, Y. P. Wu

科研成果: 期刊稿件 › 文章 › 同行评审

73 引用（Scopus）

摘要

A polymer electrolyte with interconnected pores based on poly(vinylidene difluoride-co-hexafluoropropylene) [P(VDF-HFP)] copolymer was prepared by a simple phase separation process using water as both non-solvent and pore inducer. The prepared porous membrane was characterized by SEM, XRD and DSC. With a narrow pore size distribution and low crystallinity, the resulting polymer electrolyte shows a high ionic conductivity up to 1.76 × 10^-3 S cm^-1 at room temperature and exhibits low apparent activation energy of 10.35 kJ mol^-1 for the transportation of ions. Its low cost and environmentally friendliness provide great promise for the practical application in polymer lithium-ion batteries.

源语言	英语
页（从-至）	1883-1885
页数	3
期刊	Electrochemistry Communications
卷	10
期	12
DOI	https://doi.org/10.1016/j.elecom.2008.09.035
出版状态	已出版 - 12月 2008
已对外发布	是

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10.1016/j.elecom.2008.09.035

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title = "A porous polymer electrolyte based on P(VDF-HFP) prepared by a simple phase separation process",

abstract = "A polymer electrolyte with interconnected pores based on poly(vinylidene difluoride-co-hexafluoropropylene) [P(VDF-HFP)] copolymer was prepared by a simple phase separation process using water as both non-solvent and pore inducer. The prepared porous membrane was characterized by SEM, XRD and DSC. With a narrow pore size distribution and low crystallinity, the resulting polymer electrolyte shows a high ionic conductivity up to 1.76 × 10-3 S cm-1 at room temperature and exhibits low apparent activation energy of 10.35 kJ mol-1 for the transportation of ions. Its low cost and environmentally friendliness provide great promise for the practical application in polymer lithium-ion batteries.",

keywords = "Lithium-ion battery, P(VDF-HFP), Phase separation, Polymer electrolyte, Porous membrane",

author = "Li, {G. C.} and P. Zhang and Zhang, {H. P.} and Yang, {L. C.} and Wu, {Y. P.}",

year = "2008",

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doi = "10.1016/j.elecom.2008.09.035",

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pages = "1883--1885",

journal = "Electrochemistry Communications",

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T1 - A porous polymer electrolyte based on P(VDF-HFP) prepared by a simple phase separation process

AU - Li, G. C.

AU - Zhang, P.

AU - Zhang, H. P.

AU - Yang, L. C.

AU - Wu, Y. P.

PY - 2008/12

Y1 - 2008/12

N2 - A polymer electrolyte with interconnected pores based on poly(vinylidene difluoride-co-hexafluoropropylene) [P(VDF-HFP)] copolymer was prepared by a simple phase separation process using water as both non-solvent and pore inducer. The prepared porous membrane was characterized by SEM, XRD and DSC. With a narrow pore size distribution and low crystallinity, the resulting polymer electrolyte shows a high ionic conductivity up to 1.76 × 10-3 S cm-1 at room temperature and exhibits low apparent activation energy of 10.35 kJ mol-1 for the transportation of ions. Its low cost and environmentally friendliness provide great promise for the practical application in polymer lithium-ion batteries.

AB - A polymer electrolyte with interconnected pores based on poly(vinylidene difluoride-co-hexafluoropropylene) [P(VDF-HFP)] copolymer was prepared by a simple phase separation process using water as both non-solvent and pore inducer. The prepared porous membrane was characterized by SEM, XRD and DSC. With a narrow pore size distribution and low crystallinity, the resulting polymer electrolyte shows a high ionic conductivity up to 1.76 × 10-3 S cm-1 at room temperature and exhibits low apparent activation energy of 10.35 kJ mol-1 for the transportation of ions. Its low cost and environmentally friendliness provide great promise for the practical application in polymer lithium-ion batteries.

KW - Lithium-ion battery

KW - P(VDF-HFP)

KW - Phase separation

KW - Polymer electrolyte

KW - Porous membrane

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U2 - 10.1016/j.elecom.2008.09.035

DO - 10.1016/j.elecom.2008.09.035

M3 - 文章

AN - SCOPUS:56249134215

SN - 1388-2481

VL - 10

SP - 1883

EP - 1885

JO - Electrochemistry Communications

JF - Electrochemistry Communications

IS - 12

ER -

A porous polymer electrolyte based on P(VDF-HFP) prepared by a simple phase separation process

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