A short Bi=Bi bond supported by a metalloid group 13 ligand

Ganesan Prabusankar; Christian Gemel; Pattiyil Parameswaran; Charity Flener; Gernot Frenking; Roland A. Fischer

doi:10.1002/anie.200902172

A short Bi=Bi bond supported by a metalloid group 13 ligand

Ganesan Prabusankar, Christian Gemel, Pattiyil Parameswaran, Charity Flener, Gernot Frenking, Roland A. Fischer

科研成果: 期刊稿件 › 文章 › 同行评审

80 引用（Scopus）

摘要

Bismuth goes GaGa: Dibismuthenes are derived from commercially available bismuth(III) triflate or aryloxide salts by employing [Ga(ddp)] (ddp=CH[MeC(2,6-iPr₂C₆H₃)N]₂) as an efficient reducing agent and trapping ligand. Apart from the shortest bismuth-bismuth bonds known to date, the compounds demonstrate the unique synthetic potential in main-group chemistry of lowcoordinate Group 13 compounds analogous to N-heterocyclic carbenes.

源语言	英语
页（从-至）	5526-5529
页数	4
期刊	Angewandte Chemie - International Edition
卷	48
期	30
DOI	https://doi.org/10.1002/anie.200902172
出版状态	已出版 - 13 7月 2009
已对外发布	是

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abstract = "Bismuth goes GaGa: Dibismuthenes are derived from commercially available bismuth(III) triflate or aryloxide salts by employing [Ga(ddp)] (ddp=CH[MeC(2,6-iPr2C6H3)N]2) as an efficient reducing agent and trapping ligand. Apart from the shortest bismuth-bismuth bonds known to date, the compounds demonstrate the unique synthetic potential in main-group chemistry of lowcoordinate Group 13 compounds analogous to N-heterocyclic carbenes.",

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AU - Gemel, Christian

AU - Parameswaran, Pattiyil

AU - Flener, Charity

AU - Frenking, Gernot

AU - Fischer, Roland A.

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N2 - Bismuth goes GaGa: Dibismuthenes are derived from commercially available bismuth(III) triflate or aryloxide salts by employing [Ga(ddp)] (ddp=CH[MeC(2,6-iPr2C6H3)N]2) as an efficient reducing agent and trapping ligand. Apart from the shortest bismuth-bismuth bonds known to date, the compounds demonstrate the unique synthetic potential in main-group chemistry of lowcoordinate Group 13 compounds analogous to N-heterocyclic carbenes.

AB - Bismuth goes GaGa: Dibismuthenes are derived from commercially available bismuth(III) triflate or aryloxide salts by employing [Ga(ddp)] (ddp=CH[MeC(2,6-iPr2C6H3)N]2) as an efficient reducing agent and trapping ligand. Apart from the shortest bismuth-bismuth bonds known to date, the compounds demonstrate the unique synthetic potential in main-group chemistry of lowcoordinate Group 13 compounds analogous to N-heterocyclic carbenes.

KW - Bismuth

KW - Gallium

KW - Main-group elements

KW - Metal-metal interactions

KW - Reduction

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A short Bi=Bi bond supported by a metalloid group 13 ligand

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