@article{6c85486ef17049809b4219d64b67cf6f,
title = "A stable singlet biradicaloid siladicarbene: (L:)2Si",
abstract = "A trapped silicon atom: The compound (L:)2Si with low-valent silicon was synthesized from its dichloride biradical precursor (L:) 2SiCl2 by reduction with KC8. Theoretical analysis suggest that there are two donor-acceptor σ bonds L:→Si←:L. There is one σ lone-pair orbital at Si and one π orbital which features significant π-back-donation L:←Si→:L giving short Si-C bonds.",
keywords = "DFT calculation, X-ray structure, biradicals, low oxidation state, silicon",
author = "Mondal, {Kartik Chandra} and Roesky, {Herbert W.} and Schwarzer, {Martin C.} and Gernot Frenking and Benedikt Niep{\"o}tter and Hilke Wolf and Regine Herbst-Irmer and Dietmar Stalke",
year = "2013",
month = mar,
day = "4",
doi = "10.1002/anie.201208307",
language = "英语",
volume = "52",
pages = "2963--2967",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "10",
}