Acyclic stereocontrol based on chelation-controlled ene reaction with chiral α- and β-alkoxyaldehydes

Koichi Mikami; Teck Peng Loh; Takeshi Nakai

doi:10.1016/S0957-4166(00)82265-X

Acyclic stereocontrol based on chelation-controlled ene reaction with chiral α- and β-alkoxyaldehydes

Koichi Mikami, Teck Peng Loh, Takeshi Nakai

Institute of Science Tokyo

科研成果: 期刊稿件 › 文章 › 同行评审

41 引用（Scopus）

摘要

The Lewis acid-promoted ene reactions with chiral α- and β-benzyloxy aldehydes have been developed and shown to afford high levels of both diastereofacial (chelation) selection and simple diastereoselection (anti), thus providing an efficient method for stereocontrol over three contiguous chiral centers.

源语言	英语
页（从-至）	13-16
页数	4
期刊	Tetrahedron Asymmetry
卷	1
期	1
DOI	https://doi.org/10.1016/S0957-4166(00)82265-X
出版状态	已出版 - 1990
已对外发布	是

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abstract = "The Lewis acid-promoted ene reactions with chiral α- and β-benzyloxy aldehydes have been developed and shown to afford high levels of both diastereofacial (chelation) selection and simple diastereoselection (anti), thus providing an efficient method for stereocontrol over three contiguous chiral centers.",

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AB - The Lewis acid-promoted ene reactions with chiral α- and β-benzyloxy aldehydes have been developed and shown to afford high levels of both diastereofacial (chelation) selection and simple diastereoselection (anti), thus providing an efficient method for stereocontrol over three contiguous chiral centers.

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Acyclic stereocontrol based on chelation-controlled ene reaction with chiral α- and β-alkoxyaldehydes

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