Acyclic stereocontrol based on nonchelation-controlled ene reactions with α-haloaldehydes

Koichi Mikami, Teck Peng Loh, Takeshi Nakai

科研成果: 期刊稿件文章同行评审

10 引用 (Scopus)

摘要

Aluminium(III)-promoted ene reactions with α-haloaldehydes are shown to exhibit a high anti-diastereofacial (non-chelation) selection or syn-diastereoselection to afford an efficient method for preparing stereochemically-defined β-haloalcohols including the 22R-hydroxy side chain unit in steroids.

源语言英语
页(从-至)77-78
页数2
期刊Chemical Communications
2
DOI
出版状态已出版 - 1991
已对外发布

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