Aminoaldehyde-ene reaction: Stereoselective route to β-amino alcohols

Mikami Koichi; Kaneko Masami; Loh Teck-Peng; Terada Masahiro; Nakai Takeshi

doi:10.1016/S0040-4039(00)97503-8

Aminoaldehyde-ene reaction: Stereoselective route to β-amino alcohols

Mikami Koichi, Kaneko Masami, Loh Teck-Peng, Terada Masahiro, Nakai Takeshi

Institute of Science Tokyo

科研成果: 期刊稿件 › 文章 › 同行评审

50 引用（Scopus）

摘要

The Lewis acid-promoted ene reactions with α-amino aldehydes as enophiles have been developed and shown to attain high level of syn-diastereofacial control, by the judicious choice of the amino-protecting group and the Lewis acid employed. The aldol-type reactions of ketene silyl acetals with α-amino aldehydes have also been developed to afford high level of either syn- or anti-diastereofacial control.

源语言	英语
页（从-至）	3909-3912
页数	4
期刊	Tetrahedron Letters
卷	31
期	27
DOI	https://doi.org/10.1016/S0040-4039(00)97503-8
出版状态	已出版 - 1990
已对外发布	是

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abstract = "The Lewis acid-promoted ene reactions with α-amino aldehydes as enophiles have been developed and shown to attain high level of syn-diastereofacial control, by the judicious choice of the amino-protecting group and the Lewis acid employed. The aldol-type reactions of ketene silyl acetals with α-amino aldehydes have also been developed to afford high level of either syn- or anti-diastereofacial control.",

author = "Mikami Koichi and Kaneko Masami and Loh Teck-Peng and Terada Masahiro and Nakai Takeshi",

year = "1990",

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T2 - Stereoselective route to β-amino alcohols

AU - Koichi, Mikami

AU - Masami, Kaneko

AU - Teck-Peng, Loh

AU - Masahiro, Terada

AU - Takeshi, Nakai

PY - 1990

Y1 - 1990

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AB - The Lewis acid-promoted ene reactions with α-amino aldehydes as enophiles have been developed and shown to attain high level of syn-diastereofacial control, by the judicious choice of the amino-protecting group and the Lewis acid employed. The aldol-type reactions of ketene silyl acetals with α-amino aldehydes have also been developed to afford high level of either syn- or anti-diastereofacial control.

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JF - Tetrahedron Letters

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ER -

Aminoaldehyde-ene reaction: Stereoselective route to β-amino alcohols

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