Aminosilanetrithiol RSi(SH)3: An experimental and quantum-chemical study

Yan Li; Hongping Zhu; Diego M. Andrada; Gernot Frenking; Herbert W. Roesky

doi:10.1039/c4cc00912f

Aminosilanetrithiol RSi(SH)₃: An experimental and quantum-chemical study

Yan Li, Hongping Zhu, Diego M. Andrada, Gernot Frenking, Herbert W. Roesky

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8 引用（Scopus）

摘要

An interesting aminosilanetrithiol RSi(SH)₃ (R = N(SiMe₃)-2,6-iPr₂C₆H₃) has been prepared by the reaction of lithium aminosilanetrithiolate (RSi[SLi(THF)]₃)₂ with MeCOOH. Theoretical calculations indicate that the LP(N) → σ*(Si-S) and LP(S) → σ*(Si-S) electron donations remarkably contribute to the stabilization of the Si(SH)₃ part of the molecule. RSi(SH)₃ is the first example of a stable molecule containing three SH groups attached to one element.

源语言	英语
页（从-至）	4628-4630
页数	3
期刊	Chemical Communications
卷	50
期	35
DOI	https://doi.org/10.1039/c4cc00912f
出版状态	已出版 - 4 4月 2014
已对外发布	是

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title = "Aminosilanetrithiol RSi(SH)3: An experimental and quantum-chemical study",

abstract = "An interesting aminosilanetrithiol RSi(SH)3 (R = N(SiMe3)-2,6-iPr2C6H3) has been prepared by the reaction of lithium aminosilanetrithiolate (RSi[SLi(THF)]3)2 with MeCOOH. Theoretical calculations indicate that the LP(N) → σ*(Si-S) and LP(S) → σ*(Si-S) electron donations remarkably contribute to the stabilization of the Si(SH)3 part of the molecule. RSi(SH)3 is the first example of a stable molecule containing three SH groups attached to one element.",

author = "Yan Li and Hongping Zhu and Andrada, {Diego M.} and Gernot Frenking and Roesky, {Herbert W.}",

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T1 - Aminosilanetrithiol RSi(SH)3

T2 - An experimental and quantum-chemical study

AU - Li, Yan

AU - Zhu, Hongping

AU - Andrada, Diego M.

AU - Frenking, Gernot

AU - Roesky, Herbert W.

PY - 2014/4/4

Y1 - 2014/4/4

N2 - An interesting aminosilanetrithiol RSi(SH)3 (R = N(SiMe3)-2,6-iPr2C6H3) has been prepared by the reaction of lithium aminosilanetrithiolate (RSi[SLi(THF)]3)2 with MeCOOH. Theoretical calculations indicate that the LP(N) → σ*(Si-S) and LP(S) → σ*(Si-S) electron donations remarkably contribute to the stabilization of the Si(SH)3 part of the molecule. RSi(SH)3 is the first example of a stable molecule containing three SH groups attached to one element.

AB - An interesting aminosilanetrithiol RSi(SH)3 (R = N(SiMe3)-2,6-iPr2C6H3) has been prepared by the reaction of lithium aminosilanetrithiolate (RSi[SLi(THF)]3)2 with MeCOOH. Theoretical calculations indicate that the LP(N) → σ*(Si-S) and LP(S) → σ*(Si-S) electron donations remarkably contribute to the stabilization of the Si(SH)3 part of the molecule. RSi(SH)3 is the first example of a stable molecule containing three SH groups attached to one element.

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DO - 10.1039/c4cc00912f

M3 - 文章

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SN - 1359-7345

VL - 50

SP - 4628

EP - 4630

JO - Chemical Communications

JF - Chemical Communications

IS - 35

ER -

Aminosilanetrithiol RSi(SH)3: An experimental and quantum-chemical study

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Aminosilanetrithiol RSi(SH)₃: An experimental and quantum-chemical study