An aqueous rechargeable lithium battery based on doping and intercalation mechanisms

G. J. Wang; L. C. Yang; Q. T. Qu; B. Wang; Y. P. Wu; R. Holze

doi:10.1007/s10008-009-0869-3

An aqueous rechargeable lithium battery based on doping and intercalation mechanisms

G. J. Wang, L. C. Yang, Q. T. Qu, B. Wang, Y. P. Wu, R. Holze

科研成果: 期刊稿件 › 文章 › 同行评审

71 引用（Scopus）

摘要

An aqueous rechargeable lithium battery (ARLB) using an electroactive polymer, polypyrrole (PPy), as a negative electrode; a lithium ion intercalation compound LiCoO ₂ as a positive electrode; and Li ₂SO ₄ aqueous solution as an electrolyte and its working mechanism are described. The charge/discharge process is associated with the doping/un-doping of anions at the negative electrode and intercalation/deintercalation of lithium ions at the positive electrode. The average output voltage of the PPy//LiCoO ₂ battery is about 0.85 V. This battery exhibits excellent cycling performance. This new technology solves the major problem of poor cycling life of ARLBs and will provide a new strategy to explore advanced energy storage and conversion systems.

源语言	英语
页（从-至）	865-869
页数	5
期刊	Journal of Solid State Electrochemistry
卷	14
期	5
DOI	https://doi.org/10.1007/s10008-009-0869-3
出版状态	已出版 - 5月 2010
已对外发布	是

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abstract = "An aqueous rechargeable lithium battery (ARLB) using an electroactive polymer, polypyrrole (PPy), as a negative electrode; a lithium ion intercalation compound LiCoO 2 as a positive electrode; and Li 2SO 4 aqueous solution as an electrolyte and its working mechanism are described. The charge/discharge process is associated with the doping/un-doping of anions at the negative electrode and intercalation/deintercalation of lithium ions at the positive electrode. The average output voltage of the PPy//LiCoO 2 battery is about 0.85 V. This battery exhibits excellent cycling performance. This new technology solves the major problem of poor cycling life of ARLBs and will provide a new strategy to explore advanced energy storage and conversion systems.",

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AU - Yang, L. C.

AU - Qu, Q. T.

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AU - Wu, Y. P.

AU - Holze, R.

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An aqueous rechargeable lithium battery based on doping and intercalation mechanisms

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