@article{419815330d0a4876817d7e1842ffc4e2,
title = "An efficient Bi/NH4I-mediated addition reaction for the highly diastereoselective synthesis of homoallylic alcohols in aqueous media",
abstract = "An efficient water-based bismuth-mediated addition reaction of carbonyl compound with cyclic allylic halide was developed. The reactions proceeded smoothly in aqueous DMF in the presence of ammonium iodide to afford the corresponding syn-homoallylic alcohols in moderate to good yields with excellent diastereoselectivities (>99:1 syn:anti). Reversal of product diastereoselectivity was observed when heteroaryl aldehyde possessing an adjacent chelating nitrogen atom was employed as substrate.",
keywords = "Ammonium iodide, Bismuth, Diastereoselectivity, Homoallylic alcohol, Water",
author = "Zhen Wu and Feng, {Xue Xin} and Wang, {Qing Dong} and Liu, {Xuan Yu} and Weidong Rao and Yang, {Jin Ming} and Shen, {Zhi Liang}",
note = "Publisher Copyright: {\textcopyright} 2020 The Author",
year = "2020",
month = feb,
doi = "10.1016/j.cclet.2019.07.030",
language = "英语",
volume = "31",
pages = "391--395",
journal = "Chinese Chemical Letters",
issn = "1001-8417",
publisher = "Elsevier B.V.",
number = "2",
}