An inorganic iodine-catalyzed oxidative system for the synthesis of benzimidazoles using hydrogen peroxide under ambient conditions

Chenjie Zhu, Yunyang Wei

科研成果: 期刊稿件文章同行评审

87 引用 (Scopus)

摘要

A simple and efficient catalytic oxidative system for the synthesis of benzimidazole derivatives with H2O2 in the presence of catalytic amounts of Bu4NI is developed. The formation of highly reactive iodine (III) intermediate [Bu4N]+[IO 2]- is detected by ESI-MS for the first time, and a possible mechanism for the oxidation is proposed.

源语言英语
页(从-至)1082-1086
页数5
期刊ChemSusChem
4
8
DOI
出版状态已出版 - 22 8月 2011
已对外发布

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