TY - JOUR
T1 - An N-heterocyclic carbene adduct of diatomic tin,:Sn=Sn
AU - Jones, Cameron
AU - Sidiropoulos, Anastas
AU - Holzmann, Nicole
AU - Frenking, Gernot
AU - Stasch, Andreas
PY - 2012/10/11
Y1 - 2012/10/11
N2 - Reduction of an N-heterocyclic carbene (NHC) adduct of SnCl2, viz. [(IPr)SnCl2] (IPr =:C{N(Dip)C(H)}2; Dip = 2,6-diisopropylphenyl), with a magnesium(i) dimer, has afforded the first NHC complex of a row 5 element in its diatomic form, [(IPr)SnSn(IPr)]; a computational analysis of the complex indicates that it comprises a singlet state, doubly bonded tin(0) fragment,:SnSn:, datively bonded by two NHC ligands.
AB - Reduction of an N-heterocyclic carbene (NHC) adduct of SnCl2, viz. [(IPr)SnCl2] (IPr =:C{N(Dip)C(H)}2; Dip = 2,6-diisopropylphenyl), with a magnesium(i) dimer, has afforded the first NHC complex of a row 5 element in its diatomic form, [(IPr)SnSn(IPr)]; a computational analysis of the complex indicates that it comprises a singlet state, doubly bonded tin(0) fragment,:SnSn:, datively bonded by two NHC ligands.
UR - http://www.scopus.com/inward/record.url?scp=84866239629&partnerID=8YFLogxK
U2 - 10.1039/c2cc35228a
DO - 10.1039/c2cc35228a
M3 - 文章
AN - SCOPUS:84866239629
SN - 1359-7345
VL - 48
SP - 9855
EP - 9857
JO - Chemical Communications
JF - Chemical Communications
IS - 79
ER -