An unusual two-dimensional 2-fold interpenetrating metal-organic framework based on tetranuclear manganese(II) clusters: Synthesis, structure and magnetic properties

Guang Xiang Liu; Xiao Chun Cha; Xin Long Li; Chun You Zhang; Yan Wang; Sadafumi Nishihara; Xiao Ming Ren

doi:10.1016/j.inoche.2011.03.013

An unusual two-dimensional 2-fold interpenetrating metal-organic framework based on tetranuclear manganese(II) clusters: Synthesis, structure and magnetic properties

Guang Xiang Liu, Xiao Chun Cha, Xin Long Li, Chun You Zhang, Yan Wang, Sadafumi Nishihara, Xiao Ming Ren

科研成果: 期刊稿件 › 文章 › 同行评审

15 引用（Scopus）

摘要

A novel coordination polymer, [Mn₂(DBA)₂(bix) _0.5] (1) (H₂DBA = 4,4′-methylenedibenzoic acid, bix = 1,4-bis(imidazol-1-ylmethyl)benzene), has been synthesized under hydrothermal condition, and characterized by elemental analysis, IR and single-crystal X-ray diffraction. X-ray single-crystal structural analyses reveal that complex 1 exhibits a two-dimensional 2-fold interpenetrating (4,4) frameworks based on tetranuclear [Mn₄(CO₂)₈] secondary building units, and further assembled into a three-dimensional supramolecular structure via π-π stacking interaction. Moreover, variable-temperature magnetic susceptibility studies indicate weak antiferromagnetic exchange interactions between the magnetic centers.

源语言	英语
页（从-至）	867-872
页数	6
期刊	Inorganic Chemistry Communications
卷	14
期	6
DOI	https://doi.org/10.1016/j.inoche.2011.03.013
出版状态	已出版 - 6月 2011
已对外发布	是

访问文件

10.1016/j.inoche.2011.03.013

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{187c38fbea1248779be9d26307bc492a,

title = "An unusual two-dimensional 2-fold interpenetrating metal-organic framework based on tetranuclear manganese(II) clusters: Synthesis, structure and magnetic properties",

abstract = "A novel coordination polymer, [Mn2(DBA)2(bix) 0.5] (1) (H2DBA = 4,4′-methylenedibenzoic acid, bix = 1,4-bis(imidazol-1-ylmethyl)benzene), has been synthesized under hydrothermal condition, and characterized by elemental analysis, IR and single-crystal X-ray diffraction. X-ray single-crystal structural analyses reveal that complex 1 exhibits a two-dimensional 2-fold interpenetrating (4,4) frameworks based on tetranuclear [Mn4(CO2)8] secondary building units, and further assembled into a three-dimensional supramolecular structure via π-π stacking interaction. Moreover, variable-temperature magnetic susceptibility studies indicate weak antiferromagnetic exchange interactions between the magnetic centers.",

keywords = "Crystal structure, Magnetism, Manganese(II) coordination polymer, Tetranuclear",

author = "Liu, {Guang Xiang} and Cha, {Xiao Chun} and Li, {Xin Long} and Zhang, {Chun You} and Yan Wang and Sadafumi Nishihara and Ren, {Xiao Ming}",

year = "2011",

month = jun,

doi = "10.1016/j.inoche.2011.03.013",

language = "英语",

volume = "14",

pages = "867--872",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "6",

}

TY - JOUR

T1 - An unusual two-dimensional 2-fold interpenetrating metal-organic framework based on tetranuclear manganese(II) clusters

T2 - Synthesis, structure and magnetic properties

AU - Liu, Guang Xiang

AU - Cha, Xiao Chun

AU - Li, Xin Long

AU - Zhang, Chun You

AU - Wang, Yan

AU - Nishihara, Sadafumi

AU - Ren, Xiao Ming

PY - 2011/6

Y1 - 2011/6

N2 - A novel coordination polymer, [Mn2(DBA)2(bix) 0.5] (1) (H2DBA = 4,4′-methylenedibenzoic acid, bix = 1,4-bis(imidazol-1-ylmethyl)benzene), has been synthesized under hydrothermal condition, and characterized by elemental analysis, IR and single-crystal X-ray diffraction. X-ray single-crystal structural analyses reveal that complex 1 exhibits a two-dimensional 2-fold interpenetrating (4,4) frameworks based on tetranuclear [Mn4(CO2)8] secondary building units, and further assembled into a three-dimensional supramolecular structure via π-π stacking interaction. Moreover, variable-temperature magnetic susceptibility studies indicate weak antiferromagnetic exchange interactions between the magnetic centers.

AB - A novel coordination polymer, [Mn2(DBA)2(bix) 0.5] (1) (H2DBA = 4,4′-methylenedibenzoic acid, bix = 1,4-bis(imidazol-1-ylmethyl)benzene), has been synthesized under hydrothermal condition, and characterized by elemental analysis, IR and single-crystal X-ray diffraction. X-ray single-crystal structural analyses reveal that complex 1 exhibits a two-dimensional 2-fold interpenetrating (4,4) frameworks based on tetranuclear [Mn4(CO2)8] secondary building units, and further assembled into a three-dimensional supramolecular structure via π-π stacking interaction. Moreover, variable-temperature magnetic susceptibility studies indicate weak antiferromagnetic exchange interactions between the magnetic centers.

KW - Crystal structure

KW - Magnetism

KW - Manganese(II) coordination polymer

KW - Tetranuclear

UR - http://www.scopus.com/inward/record.url?scp=79955859788&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2011.03.013

DO - 10.1016/j.inoche.2011.03.013

M3 - 文章

AN - SCOPUS:79955859788

SN - 1387-7003

VL - 14

SP - 867

EP - 872

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

An unusual two-dimensional 2-fold interpenetrating metal-organic framework based on tetranuclear manganese(II) clusters: Synthesis, structure and magnetic properties

摘要

访问文件

其它文件与链接

指纹

引用此