Anomalous threo-diastereoselectivity in allylic silane- or stannane-aldehyde condensation reactions: New interpretation of the antiperiplanar vs. synclinal problem on the transition-state conformations

Koichi Mikami; Kazuya Kawamoto; Teck Peng Loh; Takeshi Nakai

doi:10.1039/C39900001161

Anomalous threo-diastereoselectivity in allylic silane- or stannane-aldehyde condensation reactions: New interpretation of the antiperiplanar vs. synclinal problem on the transition-state conformations

Koichi Mikami, Kazuya Kawamoto, Teck Peng Loh, Takeshi Nakai

Institute of Science Tokyo

科研成果: 期刊稿件 › 文章 › 同行评审

47 引用（Scopus）

摘要

Unusual threo-diastereoselectivity has been observed in the intermolecular reactions of β-substituted crotyl-silane or-stannane with 2-benzyloxypropanal under chelation conditions, which implies preference for the synclinal over the antiperiplanar transition state.

源语言	英语
页（从-至）	1161-1163
页数	3
期刊	Chemical Communications
期	17
DOI	https://doi.org/10.1039/C39900001161
出版状态	已出版 - 1990
已对外发布	是

访问文件

10.1039/C39900001161

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{029f6e1f589b40bcb761f50c764e4df2,

title = "Anomalous threo-diastereoselectivity in allylic silane- or stannane-aldehyde condensation reactions: New interpretation of the antiperiplanar vs. synclinal problem on the transition-state conformations",

abstract = "Unusual threo-diastereoselectivity has been observed in the intermolecular reactions of β-substituted crotyl-silane or-stannane with 2-benzyloxypropanal under chelation conditions, which implies preference for the synclinal over the antiperiplanar transition state.",

author = "Koichi Mikami and Kazuya Kawamoto and Loh, {Teck Peng} and Takeshi Nakai",

year = "1990",

doi = "10.1039/C39900001161",

language = "英语",

pages = "1161--1163",

journal = "Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "17",

}

Anomalous threo-diastereoselectivity in allylic silane- or stannane-aldehyde condensation reactions: New interpretation of the antiperiplanar vs. synclinal problem on the transition-state conformations. / Mikami, Koichi; Kawamoto, Kazuya; Loh, Teck Peng 等.
在: Chemical Communications, 号码 17, 1990, 页码 1161-1163.

科研成果: 期刊稿件 › 文章 › 同行评审

TY - JOUR

T1 - Anomalous threo-diastereoselectivity in allylic silane- or stannane-aldehyde condensation reactions

T2 - New interpretation of the antiperiplanar vs. synclinal problem on the transition-state conformations

AU - Mikami, Koichi

AU - Kawamoto, Kazuya

AU - Loh, Teck Peng

AU - Nakai, Takeshi

PY - 1990

Y1 - 1990

N2 - Unusual threo-diastereoselectivity has been observed in the intermolecular reactions of β-substituted crotyl-silane or-stannane with 2-benzyloxypropanal under chelation conditions, which implies preference for the synclinal over the antiperiplanar transition state.

AB - Unusual threo-diastereoselectivity has been observed in the intermolecular reactions of β-substituted crotyl-silane or-stannane with 2-benzyloxypropanal under chelation conditions, which implies preference for the synclinal over the antiperiplanar transition state.

UR - http://www.scopus.com/inward/record.url?scp=37049067086&partnerID=8YFLogxK

U2 - 10.1039/C39900001161

DO - 10.1039/C39900001161

M3 - 文章

AN - SCOPUS:37049067086

SN - 0022-4936

SP - 1161

EP - 1163

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Anomalous threo-diastereoselectivity in allylic silane- or stannane-aldehyde condensation reactions: New interpretation of the antiperiplanar vs. synclinal problem on the transition-state conformations

摘要

访问文件

其它文件与链接

指纹

引用此