C-H activated isomers of [M(AlCp*)5] (M=Fe, Ru)

Tobias Steinke; Mirza Cokoja; Christian Gemel; Andreas Kempter; Andreas Krapp; Gernot Frenking; Ulrich Zenneck; Roland A. Fischer

doi:10.1002/anie.200462834

C-H activated isomers of [M(AlCp*)₅] (M=Fe, Ru)

Tobias Steinke, Mirza Cokoja, Christian Gemel, Andreas Kempter, Andreas Krapp, Gernot Frenking, Ulrich Zenneck, Roland A. Fischer

科研成果: 期刊稿件 › 文章 › 同行评审

69 引用（Scopus）

摘要

(Figure Presented) What are the limits for n in the case of [M(E ^lR)_n] (M = transition metal; E = Al, Ga, In)? Is n = 5 possible, maybe n = 6, or even more? A first insight is gained through the reactions of Fe⁰ and Ru⁰ precursors with excess of AlCp*, leading to C-H activated isomers of [M(AlCp*)₅] (see picture for M = Fe, gray C, white H, blue Al, red Fe, Cp* = C ₅Me₅).

源语言	英语
页（从-至）	2943-2946
页数	4
期刊	Angewandte Chemie - International Edition
卷	44
期	19
DOI	https://doi.org/10.1002/anie.200462834
出版状态	已出版 - 6 5月 2005
已对外发布	是

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abstract = "(Figure Presented) What are the limits for n in the case of [M(E lR)n] (M = transition metal; E = Al, Ga, In)? Is n = 5 possible, maybe n = 6, or even more? A first insight is gained through the reactions of Fe0 and Ru0 precursors with excess of AlCp*, leading to C-H activated isomers of [M(AlCp*)5] (see picture for M = Fe, gray C, white H, blue Al, red Fe, Cp* = C 5Me5).",

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author = "Tobias Steinke and Mirza Cokoja and Christian Gemel and Andreas Kempter and Andreas Krapp and Gernot Frenking and Ulrich Zenneck and Fischer, {Roland A.}",

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T1 - C-H activated isomers of [M(AlCp*)5] (M=Fe, Ru)

AU - Steinke, Tobias

AU - Cokoja, Mirza

AU - Gemel, Christian

AU - Kempter, Andreas

AU - Krapp, Andreas

AU - Frenking, Gernot

AU - Zenneck, Ulrich

AU - Fischer, Roland A.

PY - 2005/5/6

Y1 - 2005/5/6

N2 - (Figure Presented) What are the limits for n in the case of [M(E lR)n] (M = transition metal; E = Al, Ga, In)? Is n = 5 possible, maybe n = 6, or even more? A first insight is gained through the reactions of Fe0 and Ru0 precursors with excess of AlCp*, leading to C-H activated isomers of [M(AlCp*)5] (see picture for M = Fe, gray C, white H, blue Al, red Fe, Cp* = C 5Me5).

AB - (Figure Presented) What are the limits for n in the case of [M(E lR)n] (M = transition metal; E = Al, Ga, In)? Is n = 5 possible, maybe n = 6, or even more? A first insight is gained through the reactions of Fe0 and Ru0 precursors with excess of AlCp*, leading to C-H activated isomers of [M(AlCp*)5] (see picture for M = Fe, gray C, white H, blue Al, red Fe, Cp* = C 5Me5).

KW - Aluminum

KW - C-H activation

KW - Carbenoids

KW - Iron

KW - Ruthenium

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DO - 10.1002/anie.200462834

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AN - SCOPUS:18844362940

SN - 1433-7851

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C-H activated isomers of [M(AlCp*)5] (M=Fe, Ru)

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C-H activated isomers of [M(AlCp*)₅] (M=Fe, Ru)