TY - JOUR
T1 - Cantilever-Enhanced Photoacoustic Spectroscopy
T2 - Simultaneous Demodulation of Resonant and Nonresonant Signals for the Measurement of Dual SF6 Decomposition Components
AU - Cheng, Hongtu
AU - Feng, Jie
AU - Shen, Yang
AU - Fang, Zhi
N1 - Publisher Copyright:
© 2025 American Chemical Society.
PY - 2025/4/15
Y1 - 2025/4/15
N2 - Photoacoustic spectroscopy (PAS) gas sensing systems are generally classified into resonant and nonresonant types. However, it remains unclear whether signals at both resonant and nonresonant frequencies can be demodulated by one demodulation channel and one pass cell to achieve the simultaneous detection of two target molecules. In this study, a cantilever-enhanced photoacoustic (PA) gas detection system was utilized to measure H2S and CO2, both of which have been identified as typical fault gases in SF6 gas-insulated electrical equipment. The vibration modes of the cantilever beam at its first resonant and nonresonant frequencies were simulated and analyzed. Utilizing a laser interferometer, the vibration signals of a cantilever beam were measured. The results confirm that the resonant and nonresonant components of the vibration signal can be demodulated simultaneously. Gas detection experiments were conducted using a cantilever beam-based PAS gas sensing unit. Measurements in the ternary gas mixtures demonstrated the feasibility of simultaneously detecting H2S and CO2 by extracting components at 34 and 349 Hz. The PA signals exhibited a strong linear relationship with the gas concentrations, and the detection limits of H2S and CO2 are 2.55 and 84.69 ppm, respectively.
AB - Photoacoustic spectroscopy (PAS) gas sensing systems are generally classified into resonant and nonresonant types. However, it remains unclear whether signals at both resonant and nonresonant frequencies can be demodulated by one demodulation channel and one pass cell to achieve the simultaneous detection of two target molecules. In this study, a cantilever-enhanced photoacoustic (PA) gas detection system was utilized to measure H2S and CO2, both of which have been identified as typical fault gases in SF6 gas-insulated electrical equipment. The vibration modes of the cantilever beam at its first resonant and nonresonant frequencies were simulated and analyzed. Utilizing a laser interferometer, the vibration signals of a cantilever beam were measured. The results confirm that the resonant and nonresonant components of the vibration signal can be demodulated simultaneously. Gas detection experiments were conducted using a cantilever beam-based PAS gas sensing unit. Measurements in the ternary gas mixtures demonstrated the feasibility of simultaneously detecting H2S and CO2 by extracting components at 34 and 349 Hz. The PA signals exhibited a strong linear relationship with the gas concentrations, and the detection limits of H2S and CO2 are 2.55 and 84.69 ppm, respectively.
UR - http://www.scopus.com/inward/record.url?scp=105002658541&partnerID=8YFLogxK
U2 - 10.1021/acs.analchem.4c03543
DO - 10.1021/acs.analchem.4c03543
M3 - 文章
AN - SCOPUS:105001501909
SN - 0003-2700
VL - 97
SP - 7633
EP - 7642
JO - Analytical Chemistry
JF - Analytical Chemistry
IS - 14
ER -