Catalytic and direct methyl sulfonylation of alkenes and alkynes using a methyl sulfonyl radical generated from a DMSO, dioxygen and copper system

Yaojia Jiang, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

183 引用 (Scopus)

摘要

This paper describes an efficient method to β-keto methyl sulfones and (E)-vinyl methyl sulfones using DMSO as the substrate. The methyl sulfonyl radical generated from DMSO in the presence of catalytic Cu(i) under O2 atmosphere is believed to be involved in this reaction. Isotopic labeling and 18O2 experiments were performed to investigate the reaction mechanism.

源语言英语
页(从-至)4939-4943
页数5
期刊Chemical Science
5
12
DOI
出版状态已出版 - 1 12月 2014
已对外发布

指纹

探究 'Catalytic and direct methyl sulfonylation of alkenes and alkynes using a methyl sulfonyl radical generated from a DMSO, dioxygen and copper system' 的科研主题。它们共同构成独一无二的指纹。

引用此