Catalytic enantioselective diels-alder addition to furan provides a direct synthetic route to many chiral natural products

E. J. Corey, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

158 引用 (Scopus)

摘要

An oxazaborolidine derived from N-tosyl (αS,βR)-β-methyltryptophan (1)catalyzes the Diels-Alder reaction of 2-bromoacrolein and furan with 96:4 enantioselectivity, leading to an efficient synthesis of numerous chiral 7-oxabicyclo[2.2.1]heptene derivatives.

源语言英语
页(从-至)3979-3982
页数4
期刊Tetrahedron Letters
34
25
DOI
出版状态已出版 - 18 6月 1993
已对外发布

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