@article{d3c9def6cfca4408a083838352f40560,
title = "Catalytically Asymmetric Synthesis of 1,3-Bis(silyl)propenes via Copper-Catalyzed Double Proto-Silylations of Polar Enynes",
abstract = "A copper-catalyzed double proto-silylations of electron-deficient conjugated enynes to synthesize functional bis(silyl)propenes was developed. Under mild reaction conditions, the silylboronate PhMe2Si-Bpin reacts with the enynes via cascade proto-silylations and yields the corresponding Z-specific bis(silyl)propene products in up to 98% yield and 95% ee. In addition, the enantioselective synthesis of these compounds was also achieved by using enantiopure pyridine-oxazoline-based ligand.",
keywords = "bis(silyl)propene, conjugate addition, copper, proto-silylation, silylborane",
author = "Meng, {Fei Fan} and Xie, {Jia Hao} and Xu, {Yun He} and Loh, {Teck Peng}",
note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",
year = "2018",
month = jun,
day = "1",
doi = "10.1021/acscatal.8b00999",
language = "英语",
volume = "8",
pages = "5306--5312",
journal = "ACS Catalysis",
issn = "2155-5435",
publisher = "American Chemical Society",
number = "6",
}