Chemoselective Transfer Hydrogenation of Aldehydes and Ketones with a Heterogeneous Iridium Catalyst in Water

Zhi Wang, Lei Huang, Longfei Geng, Rizhi Chen, Weihong Xing, Yong Wang, Jun Huang

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31 引用 (Scopus)

摘要

Ir nanocatalyst Ir@CN was prepared by pyrolysis of the IrCl3 complex with 1,10-phenanthroline in the activated carbon. The iridium nanocatalyst Ir@CN was highly selective for the transfer hydrogenation of aldehydes and ketones including benzaldehyde derivatives, and the hydrogenative alkylation of C=O bonds was suppressed effectively. The iridium nanocatalyst Ir@CN is a heterogeneous catalyst and can be reused several times for the transfer hydrogenation of aldehydes and ketones.

源语言英语
文章编号1473
页(从-至)1008-1013
页数6
期刊Catalysis Letters
145
4
DOI
出版状态已出版 - 1 4月 2015

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