Coexistence of two distinct axial ligands and their thermo-induced substitution in trans-[FeL2(NCS)2][FeL2(CH 3OH)2](NCS)2 (L = 4-amino-3-(p-chlorophenyl)-5- (2-pyridyl)-1,2,4-triazole)

Lei Wang; Jing Jing Jiang; Lang Chen; Xuan Shen; Dun Ru Zhu

doi:10.1016/j.inoche.2012.11.022

Coexistence of two distinct axial ligands and their thermo-induced substitution in trans-[FeL₂(NCS)₂][FeL₂(CH ₃OH)₂](NCS)₂ (L = 4-amino-3-(p-chlorophenyl)-5- (2-pyridyl)-1,2,4-triazole)

Lei Wang, Jing Jing Jiang, Lang Chen, Xuan Shen, Dun Ru Zhu

化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

11 引用（Scopus）

摘要

A novel iron(II) complex, trans-[FeL₂(NCS)₂][FeL ₂(CH₃OH)₂](NCS)₂ (1) with 4-amino-3-(p-chlorophenyl)-5-(2-pyridyl)-1,2,4-triazole (L) has been successfully synthesized and characterized. X-ray crystallography analysis shows that 1 is the first example in the mononuclear triazole-based complexes consisting of two distinct molecules: trans-[FeL₂(NCS)₂] and trans-[FeL₂(CH₃OH)₂](NCS)₂ with each octahedral iron(II) center coordinated axial by two NCS^- ions in Fe1 but two MeOH molecules in Fe2. Moreover, 1 can lose two MeOH molecules at 220 C to form trans-[FeL₂(NCS)₂] (2) which can be transformed to 1 when recrystallizing 2 in methanol. Both 1 and 2 are high-spin species in the range of 1.8-300 K.

源语言	英语
页（从-至）	104-108
页数	5
期刊	Inorganic Chemistry Communications
卷	28
DOI	https://doi.org/10.1016/j.inoche.2012.11.022
出版状态	已出版 - 2月 2013

访问文件

10.1016/j.inoche.2012.11.022

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{82a5d906999a4593920f4a1b7885c08b,

title = "Coexistence of two distinct axial ligands and their thermo-induced substitution in trans-[FeL2(NCS)2][FeL2(CH 3OH)2](NCS)2 (L = 4-amino-3-(p-chlorophenyl)-5- (2-pyridyl)-1,2,4-triazole)",

abstract = "A novel iron(II) complex, trans-[FeL2(NCS)2][FeL 2(CH3OH)2](NCS)2 (1) with 4-amino-3-(p-chlorophenyl)-5-(2-pyridyl)-1,2,4-triazole (L) has been successfully synthesized and characterized. X-ray crystallography analysis shows that 1 is the first example in the mononuclear triazole-based complexes consisting of two distinct molecules: trans-[FeL2(NCS)2] and trans-[FeL2(CH3OH)2](NCS)2 with each octahedral iron(II) center coordinated axial by two NCS- ions in Fe1 but two MeOH molecules in Fe2. Moreover, 1 can lose two MeOH molecules at 220 C to form trans-[FeL2(NCS)2] (2) which can be transformed to 1 when recrystallizing 2 in methanol. Both 1 and 2 are high-spin species in the range of 1.8-300 K.",

keywords = "Crystal structures, Iron(II) complex, Ligand's substitution, Syntheses, Triazole",

author = "Lei Wang and Jiang, {Jing Jing} and Lang Chen and Xuan Shen and Zhu, {Dun Ru}",

year = "2013",

month = feb,

doi = "10.1016/j.inoche.2012.11.022",

language = "英语",

volume = "28",

pages = "104--108",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Coexistence of two distinct axial ligands and their thermo-induced substitution in trans-[FeL2(NCS)2][FeL2(CH 3OH)2](NCS)2 (L = 4-amino-3-(p-chlorophenyl)-5- (2-pyridyl)-1,2,4-triazole)

AU - Wang, Lei

AU - Jiang, Jing Jing

AU - Chen, Lang

AU - Shen, Xuan

AU - Zhu, Dun Ru

PY - 2013/2

Y1 - 2013/2

N2 - A novel iron(II) complex, trans-[FeL2(NCS)2][FeL 2(CH3OH)2](NCS)2 (1) with 4-amino-3-(p-chlorophenyl)-5-(2-pyridyl)-1,2,4-triazole (L) has been successfully synthesized and characterized. X-ray crystallography analysis shows that 1 is the first example in the mononuclear triazole-based complexes consisting of two distinct molecules: trans-[FeL2(NCS)2] and trans-[FeL2(CH3OH)2](NCS)2 with each octahedral iron(II) center coordinated axial by two NCS- ions in Fe1 but two MeOH molecules in Fe2. Moreover, 1 can lose two MeOH molecules at 220 C to form trans-[FeL2(NCS)2] (2) which can be transformed to 1 when recrystallizing 2 in methanol. Both 1 and 2 are high-spin species in the range of 1.8-300 K.

AB - A novel iron(II) complex, trans-[FeL2(NCS)2][FeL 2(CH3OH)2](NCS)2 (1) with 4-amino-3-(p-chlorophenyl)-5-(2-pyridyl)-1,2,4-triazole (L) has been successfully synthesized and characterized. X-ray crystallography analysis shows that 1 is the first example in the mononuclear triazole-based complexes consisting of two distinct molecules: trans-[FeL2(NCS)2] and trans-[FeL2(CH3OH)2](NCS)2 with each octahedral iron(II) center coordinated axial by two NCS- ions in Fe1 but two MeOH molecules in Fe2. Moreover, 1 can lose two MeOH molecules at 220 C to form trans-[FeL2(NCS)2] (2) which can be transformed to 1 when recrystallizing 2 in methanol. Both 1 and 2 are high-spin species in the range of 1.8-300 K.

KW - Crystal structures

KW - Iron(II) complex

KW - Ligand's substitution

KW - Syntheses

KW - Triazole

UR - http://www.scopus.com/inward/record.url?scp=84871597204&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2012.11.022

DO - 10.1016/j.inoche.2012.11.022

M3 - 文章

AN - SCOPUS:84871597204

SN - 1387-7003

VL - 28

SP - 104

EP - 108

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Coexistence of two distinct axial ligands and their thermo-induced substitution in trans-[FeL2(NCS)2][FeL2(CH 3OH)2](NCS)2 (L = 4-amino-3-(p-chlorophenyl)-5- (2-pyridyl)-1,2,4-triazole)

摘要

访问文件

其它文件与链接

指纹

引用此

Coexistence of two distinct axial ligands and their thermo-induced substitution in trans-[FeL₂(NCS)₂][FeL₂(CH ₃OH)₂](NCS)₂ (L = 4-amino-3-(p-chlorophenyl)-5- (2-pyridyl)-1,2,4-triazole)