TY - JOUR
T1 - Compounds with Planar Tetracoordinate Boron Atoms
T2 - Anti van't Hoff/Le Bel Geometries without Metal Centers
AU - Menzel, Matthias
AU - Steiner, Dirk
AU - Winkler, Heinz‐Jürgen ‐J
AU - Schweikart, Dieter
AU - Mehle, Sigrid
AU - Fau, Stefan
AU - Frenking, Gernot
AU - Massa, Werner
AU - Berndt, Armin
PY - 1995/2/21
Y1 - 1995/2/21
N2 - Electropositive elements are prerequisites for the formation of anti van't Hoff/Le Bel geometries, as evident in compounds 1, which contain planar tetracoordinate boron atoms in the CB2H framework. These compounds extend the range of molecules of this structural type to include those without metal atoms. R = CH(SiMe3)2, R′ = 2,3,5,6‐Me4C6H. (Figure Presented.)
AB - Electropositive elements are prerequisites for the formation of anti van't Hoff/Le Bel geometries, as evident in compounds 1, which contain planar tetracoordinate boron atoms in the CB2H framework. These compounds extend the range of molecules of this structural type to include those without metal atoms. R = CH(SiMe3)2, R′ = 2,3,5,6‐Me4C6H. (Figure Presented.)
KW - ab initio calculations
KW - anti van't Hoff/Le Bel geometries
KW - boron compounds
KW - borylmethyleneboranes
UR - http://www.scopus.com/inward/record.url?scp=33748227184&partnerID=8YFLogxK
U2 - 10.1002/anie.199503271
DO - 10.1002/anie.199503271
M3 - 文章
AN - SCOPUS:33748227184
SN - 1433-7851
VL - 34
SP - 327
EP - 329
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 3
ER -