TY - JOUR
T1 - Construction of two metal coordination polymers based on 1,4-terephthalate and 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene
AU - Liu, G. X.
AU - Xu, X. L.
AU - Xu, Y. Y.
AU - Nishihara, S.
AU - Ren, X. M.
PY - 2011/3
Y1 - 2011/3
N2 - Two new metal-organic frameworks, namely, Cd(BDC)(Btx) • 0.25(H 2O) (I) and Co3(BDC)3(Btx)4(H 2O)4 (II) (H2BDC = 1,4-terephthalate acid and Btx = 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene), have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, TGA, and single crystal X-ray diffraction. Complex I exhibits a scarcely reported an eight-connected (424.64) net with dinuclear cadmium clusters as secondary building units, whereas complex II displays a three-dimensional co-ordination polymer with a rare (4,6)-connected net described by the (44.62)2(48.6 7) Schläfli symbol. In addition, the luminescence measurements reveal that complex I exhibits strong fluorescent emissions in the solid state at room temperature.
AB - Two new metal-organic frameworks, namely, Cd(BDC)(Btx) • 0.25(H 2O) (I) and Co3(BDC)3(Btx)4(H 2O)4 (II) (H2BDC = 1,4-terephthalate acid and Btx = 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene), have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, TGA, and single crystal X-ray diffraction. Complex I exhibits a scarcely reported an eight-connected (424.64) net with dinuclear cadmium clusters as secondary building units, whereas complex II displays a three-dimensional co-ordination polymer with a rare (4,6)-connected net described by the (44.62)2(48.6 7) Schläfli symbol. In addition, the luminescence measurements reveal that complex I exhibits strong fluorescent emissions in the solid state at room temperature.
UR - http://www.scopus.com/inward/record.url?scp=79954458308&partnerID=8YFLogxK
U2 - 10.1134/S1070328411020035
DO - 10.1134/S1070328411020035
M3 - 文章
AN - SCOPUS:79954458308
SN - 1070-3284
VL - 37
SP - 202
EP - 210
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
IS - 3
ER -