TY - JOUR
T1 - Continuous Microflow Synthesis of Fuel Precursors from Platform Molecules Catalyzed by 1,5,7-Triazabicyclo[4.4.0]dec-5-ene
AU - Shen, Tao
AU - Tang, Jingjing
AU - Tang, Chenglun
AU - Wu, Jinglan
AU - Wang, Linfeng
AU - Zhu, Chenjie
AU - Ying, Hanjie
N1 - Publisher Copyright:
© 2017 American Chemical Society.
PY - 2017/6/16
Y1 - 2017/6/16
N2 - The first continuous flow synthesis of C8-C16 alkane fuel precursors from biobased platform molecules is reported. TBD (1,5,7-triazabicyclo[4.4.0]dec-5-ene) was found to be a recyclable and highly efficient organic base catalyst for the aldol condensation of furfural with carbonyl compounds, and the selectivity of mono- or difuryl product can be easily regulated by adjusting the molar ratio of substrates. By means of flow technique, a shorter reaction time, satisfactory output, and continuous preparation are achieved under the present procedure, representing a significant advance over the corresponding batch reaction conditions.
AB - The first continuous flow synthesis of C8-C16 alkane fuel precursors from biobased platform molecules is reported. TBD (1,5,7-triazabicyclo[4.4.0]dec-5-ene) was found to be a recyclable and highly efficient organic base catalyst for the aldol condensation of furfural with carbonyl compounds, and the selectivity of mono- or difuryl product can be easily regulated by adjusting the molar ratio of substrates. By means of flow technique, a shorter reaction time, satisfactory output, and continuous preparation are achieved under the present procedure, representing a significant advance over the corresponding batch reaction conditions.
UR - http://www.scopus.com/inward/record.url?scp=85020844942&partnerID=8YFLogxK
U2 - 10.1021/acs.oprd.7b00141
DO - 10.1021/acs.oprd.7b00141
M3 - 文章
AN - SCOPUS:85020844942
SN - 1083-6160
VL - 21
SP - 890
EP - 896
JO - Organic Process Research and Development
JF - Organic Process Research and Development
IS - 6
ER -