Controlled assembly of zero-, one- and two-dimensional metal-organic frameworks involving in situ ligand synthesis under different reaction pH

Guang Xiang Liu; Rong Yi Huang; Heng Xu; Xue Jun Kong; Liang Fang Huang; Kun Zhu; Xiao Ming Ren

doi:10.1016/j.poly.2008.04.035

Controlled assembly of zero-, one- and two-dimensional metal-organic frameworks involving in situ ligand synthesis under different reaction pH

Guang Xiang Liu, Rong Yi Huang, Heng Xu, Xue Jun Kong, Liang Fang Huang, Kun Zhu, Xiao Ming Ren

Anqing Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

34 引用（Scopus）

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Five cadmium(II) metal-organic frameworks, namely [Cd(BIPA)(daf)(H₂O)₃] · 2H₂O (1), Cd₂(BDC)₂(pdon)₂(H₂O)₂ (2), Cd(BIPA)(pdon) (3), Cd(BIPA)(daf) (4) and [Cd₂(BIPA)₂(pdon)₂] · H₂O (5) (H₂BIPA = 5-bromoisophthalic acid, H₂BDC = terephthalic acid, pdon = 1,10-phenanthroline-5,6-dione, daf = 4,5-diaza-fluoren-9-one), have been constructed from cadmium(II) salts with multi-carboxylate ligands and pdon ligands under different reaction pH. The framework structures of these polymeric complexes have been determined by the X-ray single crystal diffraction technique. The differences of the five metal-organic frameworks demonstrate that the reaction pH has an important effect on the structure of these complexes. The thermal analyses of these five complexes have been measured and discussed. Additionally, four complexes show strong fluorescence in the solid state at room temperature.

源语言	英语
页（从-至）	2327-2336
页数	10
期刊	Polyhedron
卷	27
期	11
DOI	https://doi.org/10.1016/j.poly.2008.04.035
出版状态	已出版 - 4 8月 2008
已对外发布	是

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@article{b2fc548b4ccf4c82954391cece9aa0ee,

title = "Controlled assembly of zero-, one- and two-dimensional metal-organic frameworks involving in situ ligand synthesis under different reaction pH",

abstract = "Five cadmium(II) metal-organic frameworks, namely [Cd(BIPA)(daf)(H2O)3] · 2H2O (1), Cd2(BDC)2(pdon)2(H2O)2 (2), Cd(BIPA)(pdon) (3), Cd(BIPA)(daf) (4) and [Cd2(BIPA)2(pdon)2] · H2O (5) (H2BIPA = 5-bromoisophthalic acid, H2BDC = terephthalic acid, pdon = 1,10-phenanthroline-5,6-dione, daf = 4,5-diaza-fluoren-9-one), have been constructed from cadmium(II) salts with multi-carboxylate ligands and pdon ligands under different reaction pH. The framework structures of these polymeric complexes have been determined by the X-ray single crystal diffraction technique. The differences of the five metal-organic frameworks demonstrate that the reaction pH has an important effect on the structure of these complexes. The thermal analyses of these five complexes have been measured and discussed. Additionally, four complexes show strong fluorescence in the solid state at room temperature.",

keywords = "Cadmium(II), Carboxylate ligand, Coordination polymers, In situ synthesis, Photoluminescence property",

author = "Liu, {Guang Xiang} and Huang, {Rong Yi} and Heng Xu and Kong, {Xue Jun} and Huang, {Liang Fang} and Kun Zhu and Ren, {Xiao Ming}",

year = "2008",

month = aug,

day = "4",

doi = "10.1016/j.poly.2008.04.035",

language = "英语",

volume = "27",

pages = "2327--2336",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

number = "11",

}

TY - JOUR

T1 - Controlled assembly of zero-, one- and two-dimensional metal-organic frameworks involving in situ ligand synthesis under different reaction pH

AU - Liu, Guang Xiang

AU - Huang, Rong Yi

AU - Xu, Heng

AU - Kong, Xue Jun

AU - Huang, Liang Fang

AU - Zhu, Kun

AU - Ren, Xiao Ming

PY - 2008/8/4

Y1 - 2008/8/4

N2 - Five cadmium(II) metal-organic frameworks, namely [Cd(BIPA)(daf)(H2O)3] · 2H2O (1), Cd2(BDC)2(pdon)2(H2O)2 (2), Cd(BIPA)(pdon) (3), Cd(BIPA)(daf) (4) and [Cd2(BIPA)2(pdon)2] · H2O (5) (H2BIPA = 5-bromoisophthalic acid, H2BDC = terephthalic acid, pdon = 1,10-phenanthroline-5,6-dione, daf = 4,5-diaza-fluoren-9-one), have been constructed from cadmium(II) salts with multi-carboxylate ligands and pdon ligands under different reaction pH. The framework structures of these polymeric complexes have been determined by the X-ray single crystal diffraction technique. The differences of the five metal-organic frameworks demonstrate that the reaction pH has an important effect on the structure of these complexes. The thermal analyses of these five complexes have been measured and discussed. Additionally, four complexes show strong fluorescence in the solid state at room temperature.

AB - Five cadmium(II) metal-organic frameworks, namely [Cd(BIPA)(daf)(H2O)3] · 2H2O (1), Cd2(BDC)2(pdon)2(H2O)2 (2), Cd(BIPA)(pdon) (3), Cd(BIPA)(daf) (4) and [Cd2(BIPA)2(pdon)2] · H2O (5) (H2BIPA = 5-bromoisophthalic acid, H2BDC = terephthalic acid, pdon = 1,10-phenanthroline-5,6-dione, daf = 4,5-diaza-fluoren-9-one), have been constructed from cadmium(II) salts with multi-carboxylate ligands and pdon ligands under different reaction pH. The framework structures of these polymeric complexes have been determined by the X-ray single crystal diffraction technique. The differences of the five metal-organic frameworks demonstrate that the reaction pH has an important effect on the structure of these complexes. The thermal analyses of these five complexes have been measured and discussed. Additionally, four complexes show strong fluorescence in the solid state at room temperature.

KW - Cadmium(II)

KW - Carboxylate ligand

KW - Coordination polymers

KW - In situ synthesis

KW - Photoluminescence property

UR - http://www.scopus.com/inward/record.url?scp=47049095478&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2008.04.035

DO - 10.1016/j.poly.2008.04.035

M3 - 文章

AN - SCOPUS:47049095478

SN - 0277-5387

VL - 27

SP - 2327

EP - 2336

JO - Polyhedron

JF - Polyhedron

IS - 11

ER -

Controlled assembly of zero-, one- and two-dimensional metal-organic frameworks involving in situ ligand synthesis under different reaction pH

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