Copper-catalyzed enantioselective conjugate addition of grignard reagents to methyl 4,4,4-trifluorocrotonate: Synthesis of enantioenriched trifluoromethylated compounds

Li Ying Zhang, Jia Hui Zhou, Yun He Xu, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

12 引用 (Scopus)

摘要

Copper-catalyzed enantioselective 1,4-conjugate addition of methyl 4,4,4-trifluorocrotonate with aliphatic Grignard reagents to access an asymmetric tertiary carbon center attached with a trifluoromethyl group was achieved under mild reaction conditions. The desired products could be obtained in reasonable yields and good enantioselectivities.

源语言英语
页(从-至)844-848
页数5
期刊Chemistry - An Asian Journal
10
4
DOI
出版状态已出版 - 4月 2015
已对外发布

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