Copper-catalyzed rearrangement of tertiary amines through oxidation of aliphatic C-H bonds in air or oxygen: Direct synthesis of α-amino acetals

Jie Sheng Tian, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

98 引用 (Scopus)

摘要

A surprising turn of events: Mechanistic studies, including trapping, control, and isotope-labeling experiments, led to the proposal of a rearrangement mechanism involving oxidation of aliphatic C-H bonds (see scheme; TMEDA=tetramethylethylenediamine).

源语言英语
页(从-至)8417-8420
页数4
期刊Angewandte Chemie - International Edition
49
45
DOI
出版状态已出版 - 2 11月 2010
已对外发布

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