Copper-Catalyzed Vicinal Oxyazidation and Diazidation of Styrenes under Mild Conditions: Access to Alkyl Azides

Ming Zhu Lu; Cheng Qiang Wang; Teck Peng Loh

doi:10.1021/acs.orglett.5b03130

Copper-Catalyzed Vicinal Oxyazidation and Diazidation of Styrenes under Mild Conditions: Access to Alkyl Azides

Ming Zhu Lu, Cheng Qiang Wang, Teck Peng Loh

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109 引用（Scopus）

摘要

A novel and efficient copper-catalyzed oxyazidation and diazidation of styrenes is described. The stable azidoiodine(III) reagent is used as an efficient azide radical source in this reaction. A variety of synthetically useful functional groups are compatible with the mild reaction conditions. This protocol enables the straightforward synthesis of various functionalized azides in good-to-excellent yields.

源语言	英语
页（从-至）	6110-6113
页数	4
期刊	Organic Letters
卷	17
期	24
DOI	https://doi.org/10.1021/acs.orglett.5b03130
出版状态	已出版 - 18 12月 2015
已对外发布	是

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abstract = "A novel and efficient copper-catalyzed oxyazidation and diazidation of styrenes is described. The stable azidoiodine(III) reagent is used as an efficient azide radical source in this reaction. A variety of synthetically useful functional groups are compatible with the mild reaction conditions. This protocol enables the straightforward synthesis of various functionalized azides in good-to-excellent yields.",

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AB - A novel and efficient copper-catalyzed oxyazidation and diazidation of styrenes is described. The stable azidoiodine(III) reagent is used as an efficient azide radical source in this reaction. A variety of synthetically useful functional groups are compatible with the mild reaction conditions. This protocol enables the straightforward synthesis of various functionalized azides in good-to-excellent yields.

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Copper-Catalyzed Vicinal Oxyazidation and Diazidation of Styrenes under Mild Conditions: Access to Alkyl Azides

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