Design, preparation, X-ray crystal structure, and reactivity of o-alkoxyphenyliodonium bis(methoxycarbonyl)methanide, a highly soluble carbene precursor

Chenjie Zhu; Akira Yoshimura; Lei Ji; Yunyang Wei; Victor N. Nemykin; Viktor V. Zhdankin

doi:10.1021/ol301268j

Design, preparation, X-ray crystal structure, and reactivity of o-alkoxyphenyliodonium bis(methoxycarbonyl)methanide, a highly soluble carbene precursor

Chenjie Zhu, Akira Yoshimura, Lei Ji, Yunyang Wei, Victor N. Nemykin, Viktor V. Zhdankin

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87 引用（Scopus）

摘要

The preparation, X-ray structure, and reactivity of new, highly soluble, and reactive iodonium ylides derived from malonate methyl ester and bearing an ortho substituent on the phenyl ring are reported. These new reagents show higher reactivity than common phenyliodonium ylides in the Rh-catalyzed cyclopropanation, C-H insertion, and transylidation reactions under homogeneous conditions.

源语言	英语
页（从-至）	3170-3173
页数	4
期刊	Organic Letters
卷	14
期	12
DOI	https://doi.org/10.1021/ol301268j
出版状态	已出版 - 15 6月 2012
已对外发布	是

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abstract = "The preparation, X-ray structure, and reactivity of new, highly soluble, and reactive iodonium ylides derived from malonate methyl ester and bearing an ortho substituent on the phenyl ring are reported. These new reagents show higher reactivity than common phenyliodonium ylides in the Rh-catalyzed cyclopropanation, C-H insertion, and transylidation reactions under homogeneous conditions.",

author = "Chenjie Zhu and Akira Yoshimura and Lei Ji and Yunyang Wei and Nemykin, {Victor N.} and Zhdankin, {Viktor V.}",

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AU - Zhu, Chenjie

AU - Yoshimura, Akira

AU - Ji, Lei

AU - Wei, Yunyang

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor V.

PY - 2012/6/15

Y1 - 2012/6/15

N2 - The preparation, X-ray structure, and reactivity of new, highly soluble, and reactive iodonium ylides derived from malonate methyl ester and bearing an ortho substituent on the phenyl ring are reported. These new reagents show higher reactivity than common phenyliodonium ylides in the Rh-catalyzed cyclopropanation, C-H insertion, and transylidation reactions under homogeneous conditions.

AB - The preparation, X-ray structure, and reactivity of new, highly soluble, and reactive iodonium ylides derived from malonate methyl ester and bearing an ortho substituent on the phenyl ring are reported. These new reagents show higher reactivity than common phenyliodonium ylides in the Rh-catalyzed cyclopropanation, C-H insertion, and transylidation reactions under homogeneous conditions.

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Design, preparation, X-ray crystal structure, and reactivity of o-alkoxyphenyliodonium bis(methoxycarbonyl)methanide, a highly soluble carbene precursor

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