TY - JOUR
T1 - Donor–acceptor stabilized silaformyl chloride
AU - Ghadwal, Rajendra S.
AU - Azhakar, Ramachandran
AU - Roesky, Herbert W.
AU - Pröpper, Kevin
AU - Dittrich, Birger
AU - Goedecke, Catharina
AU - Frenking, Gernot
PY - 2012/7/23
Y1 - 2012/7/23
N2 - Formyl chloride (H(Cl)C=O) is unstable at room temperature and decomposes to HCl and CO. Silicon analogue of formyl chloride, silaformyl chloride IPr·SiH(Cl)=O·B(C6F5)3 (3) (IPr = 1,3-bis(2,6-diisopropyl-phenyl)imidazol-2-ylidene), was stabilized by Lewis donor–acceptor ligands. Compound 3 is not only the first stable acyclic silacarbonyl compound but also the first silacarbonyl halide reported so far.
AB - Formyl chloride (H(Cl)C=O) is unstable at room temperature and decomposes to HCl and CO. Silicon analogue of formyl chloride, silaformyl chloride IPr·SiH(Cl)=O·B(C6F5)3 (3) (IPr = 1,3-bis(2,6-diisopropyl-phenyl)imidazol-2-ylidene), was stabilized by Lewis donor–acceptor ligands. Compound 3 is not only the first stable acyclic silacarbonyl compound but also the first silacarbonyl halide reported so far.
UR - http://www.scopus.com/inward/record.url?scp=84864266850&partnerID=8YFLogxK
U2 - 10.1039/c2cc32887a
DO - 10.1039/c2cc32887a
M3 - 文章
AN - SCOPUS:84864266850
SN - 1359-7345
VL - 48
SP - 8186
EP - 8188
JO - Chemical Communications
JF - Chemical Communications
IS - 66
ER -