Effect of Ca/Si ratio on the microstructures and properties of CaO-B 2O 3-SiO 2 glass-ceramics

Hui Shao; Hong Qing Zhou; Hai Kui Zhu; Bin Dai; Xiao Dong Shen

Effect of Ca/Si ratio on the microstructures and properties of CaO-B ₂O ₃-SiO ₂ glass-ceramics

Hui Shao, Hong Qing Zhou, Hai Kui Zhu, Bin Dai, Xiao Dong Shen

材料科学与工程学院

Nanjing Tech University

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

Influence of Ca/Si on the crystallization, microstructure and dielectric properties of CaO-B ₂O ₃-SiO ₂ glass was studied by using XRD, DSC and SEM. The results indicate that when m(Ca/Si ratio)<1.08, calcium borosilicate glass sintering temperature higher than 900°C, but it is m>1.08, CBS department of the sintering temperature of glass is far lower at 900°C. When m reaches 1.767, CBS can not be sintered; with the increase of CaO content, Ca ₂SiO ₄ crystals gradually increased, leading to the gradual reduction of wollastonite phase, resulting in gradual increase in quartz; the samples were C2, C5, C7 dielectric loss sintered <2×10 ^-3 at 1 MHz.

源语言	英语
页（从-至）	2153-2156
页数	4
期刊	Gongneng Cailiao/Journal of Functional Materials
卷	42
期	12
出版状态	已出版 - 12月 2011

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title = "Effect of Ca/Si ratio on the microstructures and properties of CaO-B 2O 3-SiO 2 glass-ceramics",

abstract = "Influence of Ca/Si on the crystallization, microstructure and dielectric properties of CaO-B 2O 3-SiO 2 glass was studied by using XRD, DSC and SEM. The results indicate that when m(Ca/Si ratio)<1.08, calcium borosilicate glass sintering temperature higher than 900°C, but it is m>1.08, CBS department of the sintering temperature of glass is far lower at 900°C. When m reaches 1.767, CBS can not be sintered; with the increase of CaO content, Ca 2SiO 4 crystals gradually increased, leading to the gradual reduction of wollastonite phase, resulting in gradual increase in quartz; the samples were C2, C5, C7 dielectric loss sintered <2×10 -3 at 1 MHz.",

keywords = "CBS glass-ceramics, Ca/Si, LTCC, Sintering properties",

author = "Hui Shao and Zhou, {Hong Qing} and Zhu, {Hai Kui} and Bin Dai and Shen, {Xiao Dong}",

year = "2011",

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journal = "Gongneng Cailiao/Journal of Functional Materials",

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TY - JOUR

T1 - Effect of Ca/Si ratio on the microstructures and properties of CaO-B 2O 3-SiO 2 glass-ceramics

AU - Shao, Hui

AU - Zhou, Hong Qing

AU - Zhu, Hai Kui

AU - Dai, Bin

AU - Shen, Xiao Dong

PY - 2011/12

Y1 - 2011/12

N2 - Influence of Ca/Si on the crystallization, microstructure and dielectric properties of CaO-B 2O 3-SiO 2 glass was studied by using XRD, DSC and SEM. The results indicate that when m(Ca/Si ratio)<1.08, calcium borosilicate glass sintering temperature higher than 900°C, but it is m>1.08, CBS department of the sintering temperature of glass is far lower at 900°C. When m reaches 1.767, CBS can not be sintered; with the increase of CaO content, Ca 2SiO 4 crystals gradually increased, leading to the gradual reduction of wollastonite phase, resulting in gradual increase in quartz; the samples were C2, C5, C7 dielectric loss sintered <2×10 -3 at 1 MHz.

AB - Influence of Ca/Si on the crystallization, microstructure and dielectric properties of CaO-B 2O 3-SiO 2 glass was studied by using XRD, DSC and SEM. The results indicate that when m(Ca/Si ratio)<1.08, calcium borosilicate glass sintering temperature higher than 900°C, but it is m>1.08, CBS department of the sintering temperature of glass is far lower at 900°C. When m reaches 1.767, CBS can not be sintered; with the increase of CaO content, Ca 2SiO 4 crystals gradually increased, leading to the gradual reduction of wollastonite phase, resulting in gradual increase in quartz; the samples were C2, C5, C7 dielectric loss sintered <2×10 -3 at 1 MHz.

KW - CBS glass-ceramics

KW - Ca/Si

KW - LTCC

KW - Sintering properties

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M3 - 文章

AN - SCOPUS:84863078909

SN - 1001-9731

VL - 42

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JO - Gongneng Cailiao/Journal of Functional Materials

JF - Gongneng Cailiao/Journal of Functional Materials

IS - 12

ER -

Effect of Ca/Si ratio on the microstructures and properties of CaO-B 2O 3-SiO 2 glass-ceramics

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Effect of Ca/Si ratio on the microstructures and properties of CaO-B ₂O ₃-SiO ₂ glass-ceramics