TY - JOUR
T1 - Effects of limestone powder on the early hydration of tricalcium aluminate
AU - Ma, Jian
AU - Liu, Xiaomin
AU - Yu, Zhuqing
AU - Shi, Hu
AU - Wu, Qingyong
AU - Shen, Xiaodong
N1 - Publisher Copyright:
© 2022, Akadémiai Kiadó, Budapest, Hungary.
PY - 2022/10
Y1 - 2022/10
N2 - To further explore the effects of limestone powder (LP) on the hydration of Portland cement as well as the formation and transformation mechanism of calcium carboaluminate phases, the hydration reaction between LP and tricalcium aluminate (C3A) is thoroughly studied in this paper. Due to the crucial influence of gypsum on the hydration of C3A, two systems are well studied, viz. the C3A–LP–H2O and the C3A–LP–CaSO4·2H2O–H2O system. The replacement levels of LP are 0, 5 mass%, 15 mass% and 25 mass% by mass of total binder. The hydration behavior of these two systems are studied using isothermal calorimetry, XRD and quantitative XRD, and chemical shrinkage. The obtained results show that more LP delays the formation of hemicarboaluminate. In the C3A–LP–CaSO4·2H2O–H2O system, the formation of calcium carboaluminate phases only begins after gypsum is consumed. Moreover, LP can reduce the chemical shrinkage resulting from the volume increase of the formation of calcium carboaluminate phases.
AB - To further explore the effects of limestone powder (LP) on the hydration of Portland cement as well as the formation and transformation mechanism of calcium carboaluminate phases, the hydration reaction between LP and tricalcium aluminate (C3A) is thoroughly studied in this paper. Due to the crucial influence of gypsum on the hydration of C3A, two systems are well studied, viz. the C3A–LP–H2O and the C3A–LP–CaSO4·2H2O–H2O system. The replacement levels of LP are 0, 5 mass%, 15 mass% and 25 mass% by mass of total binder. The hydration behavior of these two systems are studied using isothermal calorimetry, XRD and quantitative XRD, and chemical shrinkage. The obtained results show that more LP delays the formation of hemicarboaluminate. In the C3A–LP–CaSO4·2H2O–H2O system, the formation of calcium carboaluminate phases only begins after gypsum is consumed. Moreover, LP can reduce the chemical shrinkage resulting from the volume increase of the formation of calcium carboaluminate phases.
KW - Chemical shrinkage
KW - Hydration heat
KW - Limestone powder
KW - Tricalcium aluminate
KW - X-ray quantitative analysis
UR - http://www.scopus.com/inward/record.url?scp=85126235106&partnerID=8YFLogxK
U2 - 10.1007/s10973-022-11287-7
DO - 10.1007/s10973-022-11287-7
M3 - 文章
AN - SCOPUS:85126235106
SN - 1388-6150
VL - 147
SP - 10351
EP - 10362
JO - Journal of Thermal Analysis and Calorimetry
JF - Journal of Thermal Analysis and Calorimetry
IS - 19
ER -