摘要
A crystalline Ti 2Ni alloy was mechanically milled and subsequently annealed to form a non-equilibrium Ti 2Ni alloy. This non-equilibrium structure could restrain the formation of irreversible metal hydride during charging. Consequently, we demonstrated that the alloy had a discharge capacity of 336 mAh g -1, which was much higher than those of other Ti 2Ni alloys reported in the literature and also higher than that of the commercial LaNi 5-based alloy. An electrochemical hydrogen absorption-desorption mechanism of the alloy during cycling is also presented.
源语言 | 英语 |
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页(从-至) | 2149-2153 |
页数 | 5 |
期刊 | RSC Advances |
卷 | 2 |
期 | 5 |
DOI | |
出版状态 | 已出版 - 7 3月 2012 |