Enantio- and regioselective iridium-catalyzed allylic esterification

Jianping Qu; Lydia Roßberg; Günter Helmchen

doi:10.1021/ja411869r

Enantio- and regioselective iridium-catalyzed allylic esterification

Jianping Qu, Lydia Roßberg, Günter Helmchen

Heidelberg University

科研成果: 期刊稿件 › 文章 › 同行评审

50 引用（Scopus）

摘要

A highly enantioselective and regioselective Ir-catalyzed allylic esterification is described, in which branched allylic esters are synthesized directly. Carboxylates were used as nucleophiles and linear allylic phosphates as electrophiles. In some cases the allylic substitution reaction was found to be accompanied by a kinetic resolution process, which causes a change of the enantiomeric excess.

源语言	英语
页（从-至）	1272-1275
页数	4
期刊	Journal of the American Chemical Society
卷	136
期	4
DOI	https://doi.org/10.1021/ja411869r
出版状态	已出版 - 29 1月 2014
已对外发布	是

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10.1021/ja411869r

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abstract = "A highly enantioselective and regioselective Ir-catalyzed allylic esterification is described, in which branched allylic esters are synthesized directly. Carboxylates were used as nucleophiles and linear allylic phosphates as electrophiles. In some cases the allylic substitution reaction was found to be accompanied by a kinetic resolution process, which causes a change of the enantiomeric excess.",

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AB - A highly enantioselective and regioselective Ir-catalyzed allylic esterification is described, in which branched allylic esters are synthesized directly. Carboxylates were used as nucleophiles and linear allylic phosphates as electrophiles. In some cases the allylic substitution reaction was found to be accompanied by a kinetic resolution process, which causes a change of the enantiomeric excess.

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Enantio- and regioselective iridium-catalyzed allylic esterification

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