Enantioselective Cationic Polyene Cyclization vs Enantioselective Intramolecular Carbonyl-Ene Reaction

Yu Jun Zhao; Bin Li; Li Jun Serena Tan; Zhi Liang Shen; Teck Peng Loh

doi:10.1021/ja104119j

Enantioselective Cationic Polyene Cyclization vs Enantioselective Intramolecular Carbonyl-Ene Reaction

Yu Jun Zhao, Bin Li, Li Jun Serena Tan, Zhi Liang Shen, Teck Peng Loh

科研成果: 期刊稿件 › 文章 › 同行评审

76 引用（Scopus）

摘要

This paper describes highly efficient catalytic enantioselective cationic polyene cyclization and catalytic enantioselective intramolecular carbonyl-ene reaction in good to high yields with high enantioselectivities. The intimate relationship and mechanistic differences between the two enantioselective reactions were studied in detail. In addition, the cyclization products are versatile and useful building blocks for natural products and pharmaceuticals syntheses.

源语言	英语
页（从-至）	10242-10244
页数	3
期刊	Journal of the American Chemical Society
卷	132
期	30
DOI	https://doi.org/10.1021/ja104119j
出版状态	已出版 - 4 8月 2010
已对外发布	是

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abstract = "This paper describes highly efficient catalytic enantioselective cationic polyene cyclization and catalytic enantioselective intramolecular carbonyl-ene reaction in good to high yields with high enantioselectivities. The intimate relationship and mechanistic differences between the two enantioselective reactions were studied in detail. In addition, the cyclization products are versatile and useful building blocks for natural products and pharmaceuticals syntheses.",

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AU - Shen, Zhi Liang

AU - Loh, Teck Peng

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AB - This paper describes highly efficient catalytic enantioselective cationic polyene cyclization and catalytic enantioselective intramolecular carbonyl-ene reaction in good to high yields with high enantioselectivities. The intimate relationship and mechanistic differences between the two enantioselective reactions were studied in detail. In addition, the cyclization products are versatile and useful building blocks for natural products and pharmaceuticals syntheses.

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Enantioselective Cationic Polyene Cyclization vs Enantioselective Intramolecular Carbonyl-Ene Reaction

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